Multiphysics Modeling and Analysis for Dendrite Problems in Solid-State Lithium/Sodium Metal Batteries
Corresponding Author: Xiaohui Rong
Nano-Micro Letters,
Vol. 18 (2026), Article Number: 414
Abstract
The commercialization of liquid lithium-ion batteries has revolutionized the consumer electronics industry. However, conventional lithium-ion batteries with graphite anodes and organic electrolytes are approaching their intrinsic performance limits and struggle to meet the growing demands for higher energy density, reliability, and safety in electric vehicles and large-scale energy storage. Solid-state batteries utilizing lithium or sodium metal anodes are considered promising next-generation energy storage solutions. Despite this potential, the formation of dendrites during charge–discharge cycling remains a critical challenge. Dendrite growth can initiate a destructive feedback loop of crack propagation and further dendrite intrusion, ultimately leading to battery failure and performance degradation. Previous studies have predominantly focused on single physical domains, such as electrochemical, stress, or thermal fields. However, such single-physics approach limits the understanding of dendrite evolution under realistic, coupled multiphysics conditions. This review first compares the morphological characteristics of dendrites in liquid and solid-state metal batteries. It then critically examines the key factors and predictive models of dendrite formation, initially from single-physics and subsequently from an integrated multiphysics perspective. Finally, strategies for mitigating dendrite growth via multiphysics field regulation are summarized. By establishing a comprehensive framework that integrates morphology evolution, multiphysics modeling, and suppression strategies, this work provides a foundational theoretical understanding for addressing dendrite formation in solid-state lithium and sodium metal batteries.
Highlights:
1 Experimental observations of metal dendrites are systematically summarized across liquid and solid-state battery systems.
2 Dendrite evolution is elucidated from a multiphysics perspective, highlighting the coupling of electrochemical, thermal, and mechanical fields.
3 Mechanism-guided dendrite-suppression strategies are critically reviewed based on physical field regulation.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- M. Li, J. Lu, Z. Chen, K. Amine, 30 years of lithium-ion batteries. Adv. Mater. 30(33), 1800561 (2018). https://doi.org/10.1002/adma.201800561
- S. Chu, Y. Cui, N. Liu, The path towards sustainable energy. Nat. Mater. 16(1), 16–22 (2017). https://doi.org/10.1038/nmat4834
- J. Liu, Z. Bao, Y. Cui, E.J. Dufek, J.B. Goodenough et al., Pathways for practical high-energy long-cycling lithium metal batteries. Nat. Energy. 4(3), 180–186 (2019). https://doi.org/10.1038/s41560-019-0338-x
- M.M. Rahman, U. Nisar, A. Abouimrane, I. Belharouak, R. Amin, Valuation of anode materials for high-performance lithium batteries: from graphite to lithium metal and beyond. Electrochem. Energy Rev. 8(1), 14 (2025). https://doi.org/10.1007/s41918-025-00249-w
- H. Zhang, Y. Yang, D. Ren, L. Wang, X. He, Graphite as anode materials: fundamental mechanism, recent progress and advances. Energy Storage Mater. 36, 147–170 (2021). https://doi.org/10.1016/j.ensm.2020.12.027
- X.-B. Cheng, R. Zhang, C.-Z. Zhao, Q. Zhang, Toward safe lithium metal anode in rechargeable batteries: a review. Chem. Rev. 117(15), 10403–10473 (2017). https://doi.org/10.1021/acs.chemrev.7b00115
- T. Schmaltz, F. Hartmann, T. Wicke, L. Weymann, C. Neef et al., A roadmap for solid-state batteries. Adv. Energy Mater. 13(43), 2301886 (2023). https://doi.org/10.1002/aenm.202301886
- C. Zhao, L. Liu, X. Qi, Y. Lu, F. Wu et al., Solid-state sodium batteries. Adv. Energy Mater. 8(17), 1703012 (2018). https://doi.org/10.1002/aenm.201703012
- R. Usiskin, Y. Lu, J. Popovic, M. Law, P. Balaya et al., Fundamentals, status and promise of sodium-based batteries. Nat. Rev. Mater. 6(11), 1020–1035 (2021). https://doi.org/10.1038/s41578-021-00324-w
- J. Xiang, L. Yang, L. Yuan, K. Yuan, Y. Zhang et al., Alkali-metal anodes: from lab to market. Joule. 3(10), 2334–2363 (2019). https://doi.org/10.1016/j.joule.2019.07.027
- J. Janek, W.G. Zeier, A solid future for battery development. Nat. Energy. 1, 16141 (2016). https://doi.org/10.1038/nenergy.2016.141
- S. Lou, F. Zhang, C. Fu, M. Chen, Y. Ma et al., Interface issues and challenges in all-solid-state batteries: Lithium, sodium, and beyond. Adv. Mater. 33(6), e2000721 (2021). https://doi.org/10.1002/adma.202000721
- Y. Shen, Y. Zhang, S. Han, J. Wang, Z. Peng et al., Unlocking the energy capabilities of lithium metal electrode with solid-state electrolytes. Joule. 2(9), 1674–1689 (2018). https://doi.org/10.1016/j.joule.2018.06.021
- K. Yoon, S. Lee, K. Oh, K. Kang, Challenges and strategies towards practically feasible solid-state lithium metal batteries. Adv. Mater. 34(4), 2104666 (2022). https://doi.org/10.1002/adma.202104666
- K.N. Wood, M. Noked, N.P. Dasgupta, Lithium metal anodes: toward an improved understanding of coupled morphological, electrochemical, and mechanical behavior. ACS Energy Lett. 2(3), 664–672 (2017). https://doi.org/10.1021/acsenergylett.6b00650
- G. McConohy, X. Xu, T. Cui, E. Barks, S. Wang et al., Mechanical regulation of lithium intrusion probability in garnet solid electrolytes. Nat. Energy. 8(3), 241–250 (2023). https://doi.org/10.1038/s41560-022-01186-4
- Z. Ning, D.S. Jolly, G. Li, R. De Meyere, S.D. Pu et al., Visualizing plating-induced cracking in lithium-anode solid-electrolyte cells. Nat. Mater. 20(8), 1121–1129 (2021). https://doi.org/10.1038/s41563-021-00967-8
- Z. Ning, G. Li, D.L.R. Melvin, Y. Chen, J. Bu et al., Dendrite initiation and propagation in lithium metal solid-state batteries. Nature. 618(7964), 287–293 (2023). https://doi.org/10.1038/s41586-023-05970-4
- E.J. Cheng, A. Sharafi, J. Sakamoto, Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte. Electrochim. Acta. 223, 85–91 (2017). https://doi.org/10.1016/j.electacta.2016.12.018
- J. Liu, H. Yuan, H. Liu, C.-Z. Zhao, Y. Lu et al., Unlocking the failure mechanism of solid state lithium metal batteries. Adv. Energy Mater. 12(4), 2100748 (2022). https://doi.org/10.1002/aenm.202100748
- P. Wang, W. Qu, W.-L. Song, H. Chen, R. Chen et al., Electro–chemo–mechanical issues at the interfaces in solid-state lithium metal batteries. Adv. Funct. Mater. 29(27), 1900950 (2019). https://doi.org/10.1002/adfm.201900950
- H. Yu, L. Wang, Z. Zhang, Y. Li, S. Yang et al., Insight understanding of external pressure on lithium plating in commercial lithium-ion batteries. Adv. Funct. Mater. 34(42), 2406966 (2024). https://doi.org/10.1002/adfm.202406966
- P. Zou, Y. Sui, H. Zhan, C. Wang, H.L. Xin et al., Polymorph evolution mechanisms and regulation strategies of lithium metal anode under multiphysical fields. Chem. Rev. 121(10), 5986–6056 (2021). https://doi.org/10.1021/acs.chemrev.0c01100
- S. Zhang, J. Ma, S. Dong, G. Cui, Designing all-solid-state batteries by theoretical computation: a review. Electrochem. Energy Rev. 6(1), 4 (2023). https://doi.org/10.1007/s41918-022-00143-9
- L. Li, S. Basu, Y. Wang, Z. Chen, P. Hundekar et al., Self-heating–induced healing of lithium dendrites. Science. 359(6383), 1513–1516 (2018). https://doi.org/10.1126/science.aap8787
- Y. Peng, M. Ding, K. Zhang, H. Zhang, Y. Hu et al., Quantitative analysis of the coupled mechanisms of lithium plating, SEI growth, and electrolyte decomposition in fast charging battery. ACS Energy Lett. 9(12), 6022–6028 (2024). https://doi.org/10.1021/acsenergylett.4c02898
- Y. Gao, B. Zhang, Probing the mechanically stable solid electrolyte interphase and the implications in design strategies. Adv. Mater. 35(18), 2205421 (2023). https://doi.org/10.1002/adma.202205421
- T. Krauskopf, R. Dippel, H. Hartmann, K. Peppler, B. Mogwitz et al., Lithium-metal growth kinetics on LLZO garnet-type solid electrolytes. Joule. 3(8), 2030–2049 (2019). https://doi.org/10.1016/j.joule.2019.06.013
- X. Shen, R. Zhang, S. Wang, X. Chen, C. Zhao et al., The dynamic evolution of aggregated lithium dendrites in lithium metal batteries. Chin. J. Chem. Eng. 37, 137–143 (2021). https://doi.org/10.1016/j.cjche.2021.05.008
- K. Dong, Y. Xu, J. Tan, M. Osenberg, F. Sun et al., Unravelling the mechanism of lithium nucleation and growth and the interaction with the solid electrolyte interface. ACS Energy Lett. 6(5), 1719–1728 (2021). https://doi.org/10.1021/acsenergylett.1c00551
- Q. Zhang, Y. Lu, L. Miao, Q. Zhao, K. Xia et al., An alternative to lithium metal anodes: non-dendritic and highly reversible sodium metal anodes for Li-Na hybrid batteries. Angew. Chem. Int. Ed. 57(45), 14796–14800 (2018). https://doi.org/10.1002/anie.201808592
- W. Dachraoui, R.-S. Kühnel, C. Battaglia, R. Erni, Nucleation, growth and dissolution of Li metal dendrites and the formation of dead Li in Li-ion batteries investigated by operando electrochemical liquid cell scanning transmission electron microscopy. Nano Energy. 130, 110086 (2024). https://doi.org/10.1016/j.nanoen.2024.110086
- E.R. Cooper, M. Li, I. Gentle, Q. Xia, R. Knibbe, A deeper understanding of metal nucleation and growth in rechargeable metal batteries through theory and experiment. Angew. Chem. Int. Ed. 62(51), e202309247 (2023). https://doi.org/10.1002/anie.202309247
- G. Feng, Y. Shi, H. Jia, S. Risal, X. Yang et al., Progressive and instantaneous nature of lithium nucleation discovered by dynamic and operando imaging. Sci. Adv. 9(21), eadg6813 (2023). https://doi.org/10.1126/sciadv.adg6813
- C. Wang, H. Wang, L. Tao, X. Wang, P. Cao et al., Direct observation of nucleation and growth behaviors of lithium by in situ electron microscopy. ACS Energy Lett. 8(4), 1929–1935 (2023). https://doi.org/10.1021/acsenergylett.3c00180
- Z. Hui, S. Yu, S. Wang, G. Hyun, J. Holoubek et al., Nucleation processes at interfaces with both substrate and electrolyte control lithium growth. Nat. Chem. 18(1), 33–42 (2026). https://doi.org/10.1038/s41557-025-01911-y
- K. Yan, Z. Lu, H.-W. Lee, F. Xiong, P.-C. Hsu et al., Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth. Nat. Energy. 1, 16010 (2016). https://doi.org/10.1038/nenergy.2016.10
- A. Pei, G. Zheng, F. Shi, Y. Li, Y. Cui, Nanoscale nucleation and growth of electrodeposited lithium metal. Nano Lett. 17(2), 1132–1139 (2017). https://doi.org/10.1021/acs.nanolett.6b04755
- K. Ishikawa, Y. Ito, S. Harada, M. Tagawa, T. Ujihara, Crystal orientation dependence of precipitate structure of electrodeposited Li metal on Cu current collectors. Cryst. Growth Des. 17(5), 2379–2385 (2017). https://doi.org/10.1021/acs.cgd.6b01710
- P. Bai, J. Li, F.R. Brushett, M.Z. Bazant, Transition of lithium growth mechanisms in liquid electrolytes. Energy Environ. Sci. 9(10), 3221–3229 (2016). https://doi.org/10.1039/c6ee01674j
- P. Bai, J. Guo, M. Wang, A. Kushima, L. Su et al., Interactions between lithium growths and nanoporous ceramic separators. Joule. 2(11), 2434–2449 (2018). https://doi.org/10.1016/j.joule.2018.08.018
- A. Kushima, K.P. So, C. Su, P. Bai, N. Kuriyama et al., Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: root growth, dead lithium and lithium flotsams. Nano Energy. 32, 271–279 (2017). https://doi.org/10.1016/j.nanoen.2016.12.001
- M. Sadd, S. Xiong, J.R. Bowen, F. Marone, A. Matic, Investigating microstructure evolution of lithium metal during plating and stripping via operando X-ray tomographic microscopy. Nat. Commun. 14(1), 854 (2023). https://doi.org/10.1038/s41467-023-36568-z
- X.-R. Chen, Y.-X. Yao, C. Yan, R. Zhang, X.-B. Cheng et al., A diffusion: reaction competition mechanism to tailor lithium deposition for lithium-metal batteries. Angew. Chem. Int. Ed. 59(20), 7743–7747 (2020). https://doi.org/10.1002/anie.202000375
- S. Jo, B. Kwon, J. Oh, J. Lee, K. Park et al., The roles of nucleation and growth kinetics in determining Li metal morphology for Li metal batteries: columnar versus spherical growth. J. Mater. Chem. A 10(10), 5520–5529 (2022). https://doi.org/10.1039/D1TA09481E
- H. Wang, E. Matios, J. Luo, W. Li, Combining theories and experiments to understand the sodium nucleation behavior towards safe sodium metal batteries. Chem. Soc. Rev. 49(12), 3783–3805 (2020). https://doi.org/10.1039/D0CS00033G
- P.M. Bayley, N.M. Trease, C.P. Grey, Insights into electrochemical sodium metal deposition as probed with in situ 23Na NMR. J. Am. Chem. Soc. 138(6), 1955–1961 (2016). https://doi.org/10.1021/jacs.5b12423
- G. Zou, J. Wang, Y. Sun, W. Yang, T. Niu et al., A nanotwinned-alloy strategy enables fast sodium deposition dynamics. Nat. Commun. 16, 1795 (2025). https://doi.org/10.1038/s41467-025-56957-w
- R. Rodriguez, K.E. Loeffler, S.S. Nathan, J.K. Sheavly, A. Dolocan et al., In situ optical imaging of sodium electrodeposition: effects of fluoroethylene carbonate. ACS Energy Lett. 2(9), 2051–2057 (2017). https://doi.org/10.1021/acsenergylett.7b00500
- Y. Yui, M. Hayashi, J. Nakamura, In situ microscopic observation of sodium deposition/dissolution on sodium electrode. Sci. Rep. 6, 22406 (2016). https://doi.org/10.1038/srep22406
- J. Song, G. Jeong, A.-J. Lee, J.H. Park, H. Kim et al., Dendrite-free polygonal sodium deposition with excellent interfacial stability in a NaAlCl4–2SO2 inorganic electrolyte. ACS Appl. Mater. Interfaces. 7(49), 27206–27214 (2015). https://doi.org/10.1021/acsami.5b08111
- J. Hu, H. Wang, S. Wang, Y. Lei, L. Qin et al., Electrochemical deposition mechanism of sodium and potassium. Energy Storage Mater. 36, 91–98 (2021). https://doi.org/10.1016/j.ensm.2020.12.017
- L. Porz, T. Swamy, B.W. Sheldon, D. Rettenwander, T. Frömling et al., Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7(20), 1701003 (2017). https://doi.org/10.1002/aenm.201701003
- D. Cao, X. Sun, Q. Li, A. Natan, P. Xiang et al., Lithium dendrite in all-solid-state batteries: growth mechanisms, suppression strategies, and characterizations. Matter. 3(1), 57–94 (2020). https://doi.org/10.1016/j.matt.2020.03.015
- H. Liu, X.-B. Cheng, J.-Q. Huang, H. Yuan, Y. Lu et al., Controlling dendrite growth in solid-state electrolytes. ACS Energy Lett. 5(3), 833–843 (2020). https://doi.org/10.1021/acsenergylett.9b02660
- Z. Gu, D. Song, S. Luo, H. Liu, X. Sun et al., Insights into the anode-initiated and grain boundary-initiated mechanisms for dendrite formation in all-solid-state lithium metal batteries. Adv. Energy Mater. 13(45), 2302945 (2023). https://doi.org/10.1002/aenm.202302945
- F. Mo, J. Ruan, S. Sun, Z. Lian, S. Yang et al., Inside or outside: origin of lithium dendrite formation of all solid-state electrolytes. Adv. Energy Mater. 9(40), 1902123 (2019). https://doi.org/10.1002/aenm.201902123
- H. Liu, Y. Chen, P.-H. Chien, G. Amouzandeh, D. Hou et al., Dendrite formation in solid-state batteries arising from lithium plating and electrolyte reduction. Nat. Mater. 24(4), 581–588 (2025). https://doi.org/10.1038/s41563-024-02094-6
- H. Wang, H. Gao, X. Chen, J. Zhu, W. Li et al., Linking the defects to the formation and growth of Li dendrite in all-solid-state batteries. Adv. Energy Mater. 11(42), 2102148 (2021). https://doi.org/10.1002/aenm.202102148
- E. Kazyak, R. Garcia-Mendez, W.S. LePage, A. Sharafi, A.L. Davis et al., Li penetration in ceramic solid electrolytes: operando microscopy analysis of morphology, propagation, and reversibility. Matter. 2(4), 1025–1048 (2020). https://doi.org/10.1016/j.matt.2020.02.008
- C. Yildirim, F. Flatscher, S. Ganschow, A. Lassnig, C. Gammer et al., Understanding the origin of lithium dendrite branching in Li6.5La3Zr1.5Ta0.5O12 solid-state electrolyte via microscopy measurements. Nat. Commun. 15(1), 8207 (2024). https://doi.org/10.1038/s41467-024-52412-4
- L. Zhang, T. Yang, C. Du, Q. Liu, Y. Tang et al., Lithium whisker growth and stress generation in an in situ atomic force microscope-environmental transmission electron microscope set-up. Nat. Nanotechnol. 15(2), 94–98 (2020). https://doi.org/10.1038/s41565-019-0604-x
- H. Gao, X. Ai, H. Wang, W. Li, P. Wei et al., Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption. Nat. Commun. 13(1), 5050 (2022). https://doi.org/10.1038/s41467-022-32732-z
- F. Sun, L. Duchêne, M. Osenberg, S. Risse, C. Yang et al., Na electrodeposits: a new decaying mechanism for all-solid-state Na batteries revealed by synchrotron X-ray tomography. Nano Energy. 82, 105762 (2021). https://doi.org/10.1016/j.nanoen.2021.105762
- L. Geng, D. Xue, J. Yao, Q. Dai, H. Sun et al., Morphodynamics of dendrite growth in alumina based all solid-state sodium metal batteries. Energy Environ. Sci. 16(6), 2658–2668 (2023). https://doi.org/10.1039/D3EE00237C
- Z. Gao, Y. Bai, J. Feng, J. Yang, P. Liu et al., Controlling sodium dendrite growth via grain boundaries in Na3Zr2Si2PO12 electrolyte. Adv. Energy Mater. 14(20), 2304488 (2024). https://doi.org/10.1002/aenm.202304488
- S. Yang, N. Li, E. Zhao, C. Wang, J. He et al., Imaging dendrite growth in solid-state sodium batteries using fluorescence tomography technology. Sci. Adv. 10(47), eadr0676 (2024). https://doi.org/10.1126/sciadv.adr0676
- Z. Ding, Y. Tang, T. Ortmann, J.K. Eckhardt, Y. Dai et al., The impact of microstructure on filament growth at the sodium metal anode in all-solid-state sodium batteries. Adv. Energy Mater. 13(48), 2302322 (2023). https://doi.org/10.1002/aenm.202302322
- T. Ortmann, T. Fuchs, J.K. Eckhardt, Z. Ding, Q. Ma et al., Deposition of sodium metal at the copper-NaSICON interface for reservoir-free solid-state sodium batteries. Adv. Energy Mater. 14(15), 2302729 (2024). https://doi.org/10.1002/aenm.202302729
- Q. Liu, L. Zhang, H. Sun, L. Geng, Y. Li et al., In situ observation of sodium dendrite growth and concurrent mechanical property measurements using an environmental transmission electron microscopy–atomic force microscopy (ETEM-AFM) platform. ACS Energy Lett. 5(8), 2546–2559 (2020). https://doi.org/10.1021/acsenergylett.0c01214
- A. Wang, Q. Zhang, W. Li, K. Zhang, C. Dong et al., Electrochemical–mechanical evolution of dendrites and cracks in Na3Zr2Si2PO12 ceramic solid electrolytes. Adv. Energy Mater. 15(36), e02156 (2025). https://doi.org/10.1002/aenm.202502156
- Q. Ma, T. Ortmann, A. Yang, D. Sebold, S. Burkhardt et al., Enhancing the dendrite tolerance of NaSICON electrolytes by suppressing edge growth of Na electrode along ceramic surface. Adv. Energy Mater. 12(40), 2201680 (2022). https://doi.org/10.1002/aenm.202201680
- H. Liu, X.-B. Cheng, Z. Jin, R. Zhang, G. Wang et al., Recent advances in understanding dendrite growth on alkali metal anodes. EnergyChem. 1(1), 100003 (2019). https://doi.org/10.1016/j.enchem.2019.100003
- M. Wang, X. Guo, R. Luo, X. Jiang, Y. Tang et al., The nucleation and growth mechanism of spherical Li for advanced Li metal anodes—a review. Chem. Commun. 61(19), 3777–3793 (2025). https://doi.org/10.1039/D4CC06729K
- Y. Liu, X. Xu, M. Sadd, O.O. Kapitanova, V.A. Krivchenko et al., Insight into the critical role of exchange current density on electrodeposition behavior of lithium metal. Adv. Sci. 8(5), 2003301 (2021). https://doi.org/10.1002/advs.202003301
- A.J. Bard, L.R. Faulkner, Electrochemical Methods: Fundamentals and Applications, 2nd edn. (Wiley, New York, 2001), pp.305–316
- Y. Lu, C.-Z. Zhao, H. Yuan, X.-B. Cheng, J.-Q. Huang et al., Critical current density in solid-state lithium metal batteries: mechanism, influences, and strategies. Adv. Funct. Mater. 31(18), 2009925 (2021). https://doi.org/10.1002/adfm.202009925
- P. Yang, Dendrite growth on metal anodes: a unified framework bridging diffusion and interfacial kinetics. ACS Energy Lett. 10(10), 5040–5046 (2025). https://doi.org/10.1021/acsenergylett.5c02663
- S. Luo, Y. Zhang, X. Liu, Z. Wang, A. Fan et al., Thermal behavior of Li electrode in all-solid-state batteries and improved performance by temperature modulation. Int. J. Heat Mass Transf. 199, 123450 (2022). https://doi.org/10.1016/j.ijheatmasstransfer.2022.123450
- B.S. Vishnugopi, F. Hao, A. Verma, P.P. Mukherjee, Double-edged effect of temperature on lithium dendrites. ACS Appl. Mater. Interfaces. 12(21), 23931–23938 (2020). https://doi.org/10.1021/acsami.0c04355
- M. Tao, X. Chen, H. Lin, Y. Jin, P. Shan et al., Clarifying the temperature-dependent lithium deposition/stripping process and the evolution of inactive Li in lithium metal batteries. ACS Nano. 17(23), 24104–24114 (2023). https://doi.org/10.1021/acsnano.3c09120
- K. Yan, J. Wang, S. Zhao, D. Zhou, B. Sun et al., Temperature-dependent nucleation and growth of dendrite-free lithium metal anodes. Angew. Chem. Int. Ed. 58(33), 11364–11368 (2019). https://doi.org/10.1002/anie.201905251
- A. Sharafi, H.M. Meyer, J. Nanda, J. Wolfenstine, J. Sakamoto, Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density. J. Power. Sources. 302, 135–139 (2016). https://doi.org/10.1016/j.jpowsour.2015.10.053
- C.D. Fincher, C.E. Athanasiou, C. Gilgenbach, M. Wang, B.W. Sheldon et al., Controlling dendrite propagation in solid-state batteries with engineered stress. Joule. 6(12), 2794–2809 (2022). https://doi.org/10.1016/j.joule.2022.10.011
- S. Kalnaus, N.J. Dudney, A.S. Westover, E. Herbert, S. Hackney, Solid-state batteries: the critical role of mechanics. Science. 381(6664), eabg5998 (2023). https://doi.org/10.1126/science.abg5998
- H. Xu, S. Yang, B. Li, Pressure effects and countermeasures in solid-state batteries: a comprehensive review. Adv. Energy Mater. 14(16), 2303539 (2024). https://doi.org/10.1002/aenm.202303539
- J. Hu, Z. Sun, Y. Gao, P. Li, Y. Wu et al., 3D stress mapping reveals the origin of lithium-deposition heterogeneity in solid-state lithium-metal batteries. Cell Rep. Phys. Sci. 3(7), 100938 (2022). https://doi.org/10.1016/j.xcrp.2022.100938
- Q. Li, H. Liu, Y. Ye, K.J. Li, F. Wu et al., The critical importance of stack pressure in batteries. Nat. Energy. 10(9), 1064–1073 (2025). https://doi.org/10.1038/s41560-025-01820-x
- P. Barai, K. Higa, V. Srinivasan, Effect of initial state of lithium on the propensity for dendrite formation: a theoretical study. J. Electrochem. Soc. 164(2), A180–A189 (2017). https://doi.org/10.1149/2.0661702jes
- P. Barai, K. Higa, V. Srinivasan, Lithium dendrite growth mechanisms in polymer electrolytes and prevention strategies. Phys. Chem. Chem. Phys. 19(31), 20493–20505 (2017). https://doi.org/10.1039/c7cp03304d
- X. Wang, W. Zeng, L. Hong, W. Xu, H. Yang et al., Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates. Nat. Energy. 3(3), 227–235 (2018). https://doi.org/10.1038/s41560-018-0104-5
- J. Becherer, D. Kramer, R. Mönig, The growth mechanism of lithium dendrites and its coupling to mechanical stress. J. Mater. Chem. A 10(10), 5530–5539 (2022). https://doi.org/10.1039/D1TA10920K
- B. Zhang, B. Yuan, X. Yan, X. Han, J. Zhang et al., Atomic mechanism of lithium dendrite penetration in solid electrolytes. Nat. Commun. 16, 1906 (2025). https://doi.org/10.1038/s41467-025-57259-x
- X. Shen, R. Zhang, P. Shi, X. Chen, Q. Zhang, How does external pressure shape Li dendrites in Li metal batteries? Adv. Energy Mater. 11(10), 2003416 (2021). https://doi.org/10.1002/aenm.202003416
- A. Gupta, E. Kazyak, N. Craig, J. Christensen, N.P. Dasgupta et al., Evaluating the effects of temperature and pressure on Li/PEO-LiTFSI interfacial stability and kinetics. J. Electrochem. Soc. 165(11), A2801–A2806 (2018). https://doi.org/10.1149/2.0901811jes
- P. Barai, K. Higa, V. Srinivasan, Impact of external pressure and electrolyte transport properties on lithium dendrite growth. J. Electrochem. Soc. 165(11), A2654–A2666 (2018). https://doi.org/10.1149/2.0651811jes
- J. Cui, X. Chen, Z. Zhou, M. Zuo, Y. Xiao et al., Effect of continuous pressures on electrochemical performance of Si anodes. Mater. Today Energy. 20, 100632 (2021). https://doi.org/10.1016/j.mtener.2020.100632
- J.-M. Doux, H. Nguyen, D.H.S. Tan, A. Banerjee, X. Wang et al., Stack pressure considerations for room-temperature all-solid-state lithium metal batteries. Adv. Energy Mater. 10, 1903253 (2020). https://doi.org/10.1002/aenm.201903253
- X. Cao, Y. Lu, X. Song, Z. Yuan, F. Wang, Perspective of unstable solid electrolyte interphase induced lithium dendrite growth: role of thermal effect. Electrochim. Acta. 439, 141722 (2023). https://doi.org/10.1016/j.electacta.2022.141722
- Z. Hong, V. Viswanathan, Prospect of thermal shock induced healing of lithium dendrite. ACS Energy Lett. 4(5), 1012–1019 (2019). https://doi.org/10.1021/acsenergylett.9b00433
- Y. Li, W. Zhao, G. Zhang, S. Shi, Unified picture on temperature dependence of lithium dendrite growth via phase-field simulation. Energy Mater. Adv. 4, 53 (2023). https://doi.org/10.34133/energymatadv.0053
- A. Jana, S.I. Woo, K.S.N. Vikrant, R.E. García, Electrochemomechanics of lithium dendrite growth. Energy Environ. Sci. 12(12), 3595–3607 (2019). https://doi.org/10.1039/c9ee01864f
- J.A. Dawson, P. Canepa, T. Famprikis, C. Masquelier, M.S. Islam, Atomic-scale influence of grain boundaries on Li-ion conduction in solid electrolytes for all-solid-state batteries. J. Am. Chem. Soc. 140(1), 362–368 (2018). https://doi.org/10.1021/jacs.7b10593
- D. Bistri, C.V. Di Leo, A continuum electro-chemo-mechanical gradient theory coupled with damage: application to Li-metal filament growth in all-solid-state batteries. J. Mech. Phys. Solids. 174, 105252 (2023). https://doi.org/10.1016/j.jmps.2023.105252
- F. Hao, W. Wang, P.P. Mukherjee, Mechano-electrochemical interaction in solid-state lithium batteries. J. Electrochem. Soc. 167(8), 080513 (2020). https://doi.org/10.1149/1945-7111/ab8a98
- R. Raj, J. Wolfenstine, Current limit diagrams for dendrite formation in solid-state electrolytes for Li-ion batteries. J. Power. Sources. 343, 119–126 (2017). https://doi.org/10.1016/j.jpowsour.2017.01.037
- G. Li, C.W. Monroe, Dendrite nucleation in lithium-conductive ceramics. Phys. Chem. Chem. Phys. 21(36), 20354–20359 (2019). https://doi.org/10.1039/c9cp03884a
- P. Barai, K. Higa, A.T. Ngo, L.A. Curtiss, V. Srinivasan, Mechanical stress induced current focusing and fracture in grain boundaries. J. Electrochem. Soc. 166(10), A1752–A1762 (2019). https://doi.org/10.1149/2.0321910jes
- P. Barai, A.T. Ngo, B. Narayanan, K. Higa, L.A. Curtiss et al., The role of local inhomogeneities on dendrite growth in LLZO-based solid electrolytes. J. Electrochem. Soc. 167(10), 100537 (2020). https://doi.org/10.1149/1945-7111/ab9b08
- R. Raj, Stack pressure and critical current density in Li-metal cells: the role of mechanical deformation. Acta Mater. 215, 117076 (2021). https://doi.org/10.1016/j.actamat.2021.117076
- A. Singla, K.G. Naik, B.S. Vishnugopi, P.P. Mukherjee, Chemo-mechanics interplay dictates interface instability and asymmetry in plating and stripping of sodium metal electrodes. Adv. Funct. Mater. 35(13), 2418033 (2025). https://doi.org/10.1002/adfm.202418033
- W. Zaman, L. Zhao, T. Martin, X. Zhang, Z. Wang et al., Temperature and pressure effects on unrecoverable voids in Li metal solid-state batteries. ACS Appl. Mater. Interfaces. 15(31), 37401–37409 (2023). https://doi.org/10.1021/acsami.3c05886
- D.S. Jolly, Z. Ning, G.O. Hartley, B. Liu, D.L.R. Melvin et al., Temperature dependence of lithium anode voiding in argyrodite solid-state batteries. ACS Appl. Mater. Interfaces. 13(19), 22708–22716 (2021). https://doi.org/10.1021/acsami.1c06706
- M. Zhang, K. Tantratian, S.-Y. Ham, Z. Wang, M. Chouchane et al., Grain selection growth of soft metal in electrochemical processes. Joule. 9(4), 101847 (2025). https://doi.org/10.1016/j.joule.2025.101847
- D. Chatterjee, K.G. Naik, B.S. Vishnugopi, P.P. Mukherjee, Electrodeposition stability landscape for solid–solid interfaces. Adv. Sci. 11(6), 2307455 (2024). https://doi.org/10.1002/advs.202307455
- A. Verma, H. Kawakami, H. Wada, A. Hirowatari, N. Ikeda et al., Microstructure and pressure-driven electrodeposition stability in solid-state batteries. Cell Rep. Phys. Sci. 2(1), 100301 (2021). https://doi.org/10.1016/j.xcrp.2020.100301
- J. Pei, X. Bai, P. Xue, L. Ma, R. Long et al., All-solid-state battery safety in abnormal thermal situations: crack propagation and lithium dendrite growth. Nano Res. Energy. 4(2), e9120155 (2025). https://doi.org/10.26599/nre.2025.9120155
- L. He, Q. Sun, L. Lu, S. Adams, Understanding and preventing dendrite growth in lithium metal batteries. ACS Appl. Mater. Interfaces. 13(29), 34320–34331 (2021). https://doi.org/10.1021/acsami.1c08268
- G. Zhao, C. Luo, B. Wu, M. Zhang, H. Wang et al., Low-temperature in situ lithiation construction of a lithiophilic p-selective interlayer for solid-state lithium metal batteries. ACS Appl. Mater. Interfaces 15(43), 50508–50521 (2023). https://doi.org/10.1021/acsami.3c11477
- L. Suo, Y.-S. Hu, H. Li, M. Armand, L. Chen, A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries. Nat. Commun. 4, 1481 (2013). https://doi.org/10.1038/ncomms2513
- Y.-S. Hu, Y. Lu, The mystery of electrolyte concentration: from superhigh to ultralow. ACS Energy Lett. 5(11), 3633–3636 (2020). https://doi.org/10.1021/acsenergylett.0c02234
- F. Chen, X. Wang, M. Armand, M. Forsyth, Cationic polymer-in-salt electrolytes for fast metal ion conduction and solid-state battery applications. Nat. Mater. 21(10), 1175–1182 (2022). https://doi.org/10.1038/s41563-022-01319-w
- L. Zhang, X. Yin, S. Shen, Y. Liu, T. Li et al., Simultaneously homogenized electric field and ionic flux for reversible ultrahigh-areal-capacity Li deposition. Nano Lett. 20(8), 5662–5669 (2020). https://doi.org/10.1021/acs.nanolett.0c00797
- R. Zhang, X. Shen, X.-B. Cheng, Q. Zhang, The dendrite growth in 3D structured lithium metal anodes: electron or ion transfer limitation? Energy Storage Mater. 23, 556–565 (2019). https://doi.org/10.1016/j.ensm.2019.03.029
- J. Pu, J. Li, K. Zhang, T. Zhang, C. Li et al., Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits. Nat. Commun. 10(1), 1896 (2019). https://doi.org/10.1038/s41467-019-09932-1
- Z. Liang, M.S. Nafis, S. Cho, F. Guo, H. Zhou et al., Pressure-tolerant 3D anodes enable short-circuit prevention and low heat generation in argyrodite solid-state batteries. ACS Energy Lett. 10(5), 2461–2467 (2025). https://doi.org/10.1021/acsenergylett.5c00985
- B. Yi, Z. Wei, W. Jia, G. Sun, W. Si et al., Nonstoichiometry induced amorphous grain boundary of Na5SmSi4O12 solid-state electrolyte for long-life dendrite-free sodium metal battery. Nano Lett. 24(29), 8911–8919 (2024). https://doi.org/10.1021/acs.nanolett.4c01743
- S. Zhao, H. Wang, Y. Wang, Y. Li, L. Zheng et al., Inhibiting microdomain crystallinity of polymer-based electrolytes toward high-performance solid-state sodium batteries. Nano Energy. 145, 111473 (2025). https://doi.org/10.1016/j.nanoen.2025.111473
- A. Parejiya, R. Amin, M.B. Dixit, R. Essehli, C.J. Jafta et al., Improving contact impedance via electrochemical pulses applied to lithium–solid electrolyte interface in solid-state batteries. ACS Energy Lett. 6(10), 3669–3675 (2021). https://doi.org/10.1021/acsenergylett.1c01573
- Q. Li, S. Tan, L. Li, Y. Lu, Y. He, Understanding the molecular mechanism of pulse current charging for stable lithium-metal batteries. Sci. Adv. 3(7), e1701246 (2017). https://doi.org/10.1126/sciadv.1701246
- D. Qiao, X. Liu, R. Dou, Z. Wen, W. Zhou et al., Quantitative analysis of the inhibition effect of rising temperature and pulse charging on lithium dendrite growth. J. Energy Storage. 49, 104137 (2022). https://doi.org/10.1016/j.est.2022.104137
- A. Aryanfar, D. Brooks, B.V. Merinov, W.A. Goddard III., A.J. Colussi et al., Dynamics of lithium dendrite growth and inhibition: pulse charging experiments and Monte Carlo calculations. J. Phys. Chem. Lett. 5(10), 1721–1726 (2014). https://doi.org/10.1021/jz500207a
- V. Reisecker, F. Flatscher, L. Porz, C. Fincher, J. Todt et al., Effect of pulse-current-based protocols on the lithium dendrite formation and evolution in all-solid-state batteries. Nat. Commun. 14, 2432 (2023). https://doi.org/10.1038/s41467-023-37476-y
- Y. Chen, X. Dou, K. Wang, Y. Han, Lithium dendrites inhibition via diffusion enhancement. Adv. Energy Mater. 9(17), 1900019 (2019). https://doi.org/10.1002/aenm.201900019
- K. Shen, Z. Wang, X. Bi, Y. Ying, D. Zhang et al., Magnetic field–suppressed lithium dendrite growth for stable lithium-metal batteries. Adv. Energy Mater. 9(20), 1900260 (2019). https://doi.org/10.1002/aenm.201900260
- Y. Chen, X. Dou, K. Wang, Y. Han, Magnetically enhancing diffusion for dendrite-free and long-term stable lithium metal anodes. Green Energy Environ. 7(5), 965–974 (2022). https://doi.org/10.1016/j.gee.2020.12.014
- R.S. Longchamps, S. Ge, Z.J. Trdinich, J. Liao, C.-Y. Wang, Battery electronification: intracell actuation and thermal management. Nat. Commun. 15(1), 5373 (2024). https://doi.org/10.1038/s41467-024-49389-5
- S. Chen, X. Hu, L. Nie, Y. Yu, W. Liu, Recycling of garnet solid electrolytes with lithium-dendrite penetration by thermal healing. Sci. China Mater. 66(6), 2192–2198 (2023). https://doi.org/10.1007/s40843-022-2371-9
- Z. Yu, C. Gan, S. Song, P. Guduru, K.-S. Kim et al., Dendrite suppression in garnet electrolytes via thermally induced compressive stress. Joule. 10(1), 102232 (2026). https://doi.org/10.1016/j.joule.2025.102232
- Z. Gao, J. Yang, G. Li, T. Ferber, J. Feng et al., TiO2 as second phase in Na3Zr2Si2PO12 to suppress dendrite growth in sodium metal solid-state batteries. Adv. Energy Mater. 12(9), 2103607 (2022). https://doi.org/10.1002/aenm.202103607
- M. Feng, C.-T. Yang, Y. Qi, The critical stack pressure to alter void generation at Li/solid-electrolyte interfaces during stripping. J. Electrochem. Soc. 169(9), 090526 (2022). https://doi.org/10.1149/1945-7111/ac91aa
- L. Ye, X. Li, A dynamic stability design strategy for lithium metal solid state batteries. Nature. 593(7858), 218–222 (2021). https://doi.org/10.1038/s41586-021-03486-3
- K. Yan, S. Zhao, J. Zhang, J. Safaei, X. Yu et al., Dendrite-free sodium metal batteries enabled by the release of contact strain on flexible and sodiophilic matrix. Nano Lett. 20(8), 6112–6119 (2020). https://doi.org/10.1021/acs.nanolett.0c02215
References
M. Li, J. Lu, Z. Chen, K. Amine, 30 years of lithium-ion batteries. Adv. Mater. 30(33), 1800561 (2018). https://doi.org/10.1002/adma.201800561
S. Chu, Y. Cui, N. Liu, The path towards sustainable energy. Nat. Mater. 16(1), 16–22 (2017). https://doi.org/10.1038/nmat4834
J. Liu, Z. Bao, Y. Cui, E.J. Dufek, J.B. Goodenough et al., Pathways for practical high-energy long-cycling lithium metal batteries. Nat. Energy. 4(3), 180–186 (2019). https://doi.org/10.1038/s41560-019-0338-x
M.M. Rahman, U. Nisar, A. Abouimrane, I. Belharouak, R. Amin, Valuation of anode materials for high-performance lithium batteries: from graphite to lithium metal and beyond. Electrochem. Energy Rev. 8(1), 14 (2025). https://doi.org/10.1007/s41918-025-00249-w
H. Zhang, Y. Yang, D. Ren, L. Wang, X. He, Graphite as anode materials: fundamental mechanism, recent progress and advances. Energy Storage Mater. 36, 147–170 (2021). https://doi.org/10.1016/j.ensm.2020.12.027
X.-B. Cheng, R. Zhang, C.-Z. Zhao, Q. Zhang, Toward safe lithium metal anode in rechargeable batteries: a review. Chem. Rev. 117(15), 10403–10473 (2017). https://doi.org/10.1021/acs.chemrev.7b00115
T. Schmaltz, F. Hartmann, T. Wicke, L. Weymann, C. Neef et al., A roadmap for solid-state batteries. Adv. Energy Mater. 13(43), 2301886 (2023). https://doi.org/10.1002/aenm.202301886
C. Zhao, L. Liu, X. Qi, Y. Lu, F. Wu et al., Solid-state sodium batteries. Adv. Energy Mater. 8(17), 1703012 (2018). https://doi.org/10.1002/aenm.201703012
R. Usiskin, Y. Lu, J. Popovic, M. Law, P. Balaya et al., Fundamentals, status and promise of sodium-based batteries. Nat. Rev. Mater. 6(11), 1020–1035 (2021). https://doi.org/10.1038/s41578-021-00324-w
J. Xiang, L. Yang, L. Yuan, K. Yuan, Y. Zhang et al., Alkali-metal anodes: from lab to market. Joule. 3(10), 2334–2363 (2019). https://doi.org/10.1016/j.joule.2019.07.027
J. Janek, W.G. Zeier, A solid future for battery development. Nat. Energy. 1, 16141 (2016). https://doi.org/10.1038/nenergy.2016.141
S. Lou, F. Zhang, C. Fu, M. Chen, Y. Ma et al., Interface issues and challenges in all-solid-state batteries: Lithium, sodium, and beyond. Adv. Mater. 33(6), e2000721 (2021). https://doi.org/10.1002/adma.202000721
Y. Shen, Y. Zhang, S. Han, J. Wang, Z. Peng et al., Unlocking the energy capabilities of lithium metal electrode with solid-state electrolytes. Joule. 2(9), 1674–1689 (2018). https://doi.org/10.1016/j.joule.2018.06.021
K. Yoon, S. Lee, K. Oh, K. Kang, Challenges and strategies towards practically feasible solid-state lithium metal batteries. Adv. Mater. 34(4), 2104666 (2022). https://doi.org/10.1002/adma.202104666
K.N. Wood, M. Noked, N.P. Dasgupta, Lithium metal anodes: toward an improved understanding of coupled morphological, electrochemical, and mechanical behavior. ACS Energy Lett. 2(3), 664–672 (2017). https://doi.org/10.1021/acsenergylett.6b00650
G. McConohy, X. Xu, T. Cui, E. Barks, S. Wang et al., Mechanical regulation of lithium intrusion probability in garnet solid electrolytes. Nat. Energy. 8(3), 241–250 (2023). https://doi.org/10.1038/s41560-022-01186-4
Z. Ning, D.S. Jolly, G. Li, R. De Meyere, S.D. Pu et al., Visualizing plating-induced cracking in lithium-anode solid-electrolyte cells. Nat. Mater. 20(8), 1121–1129 (2021). https://doi.org/10.1038/s41563-021-00967-8
Z. Ning, G. Li, D.L.R. Melvin, Y. Chen, J. Bu et al., Dendrite initiation and propagation in lithium metal solid-state batteries. Nature. 618(7964), 287–293 (2023). https://doi.org/10.1038/s41586-023-05970-4
E.J. Cheng, A. Sharafi, J. Sakamoto, Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte. Electrochim. Acta. 223, 85–91 (2017). https://doi.org/10.1016/j.electacta.2016.12.018
J. Liu, H. Yuan, H. Liu, C.-Z. Zhao, Y. Lu et al., Unlocking the failure mechanism of solid state lithium metal batteries. Adv. Energy Mater. 12(4), 2100748 (2022). https://doi.org/10.1002/aenm.202100748
P. Wang, W. Qu, W.-L. Song, H. Chen, R. Chen et al., Electro–chemo–mechanical issues at the interfaces in solid-state lithium metal batteries. Adv. Funct. Mater. 29(27), 1900950 (2019). https://doi.org/10.1002/adfm.201900950
H. Yu, L. Wang, Z. Zhang, Y. Li, S. Yang et al., Insight understanding of external pressure on lithium plating in commercial lithium-ion batteries. Adv. Funct. Mater. 34(42), 2406966 (2024). https://doi.org/10.1002/adfm.202406966
P. Zou, Y. Sui, H. Zhan, C. Wang, H.L. Xin et al., Polymorph evolution mechanisms and regulation strategies of lithium metal anode under multiphysical fields. Chem. Rev. 121(10), 5986–6056 (2021). https://doi.org/10.1021/acs.chemrev.0c01100
S. Zhang, J. Ma, S. Dong, G. Cui, Designing all-solid-state batteries by theoretical computation: a review. Electrochem. Energy Rev. 6(1), 4 (2023). https://doi.org/10.1007/s41918-022-00143-9
L. Li, S. Basu, Y. Wang, Z. Chen, P. Hundekar et al., Self-heating–induced healing of lithium dendrites. Science. 359(6383), 1513–1516 (2018). https://doi.org/10.1126/science.aap8787
Y. Peng, M. Ding, K. Zhang, H. Zhang, Y. Hu et al., Quantitative analysis of the coupled mechanisms of lithium plating, SEI growth, and electrolyte decomposition in fast charging battery. ACS Energy Lett. 9(12), 6022–6028 (2024). https://doi.org/10.1021/acsenergylett.4c02898
Y. Gao, B. Zhang, Probing the mechanically stable solid electrolyte interphase and the implications in design strategies. Adv. Mater. 35(18), 2205421 (2023). https://doi.org/10.1002/adma.202205421
T. Krauskopf, R. Dippel, H. Hartmann, K. Peppler, B. Mogwitz et al., Lithium-metal growth kinetics on LLZO garnet-type solid electrolytes. Joule. 3(8), 2030–2049 (2019). https://doi.org/10.1016/j.joule.2019.06.013
X. Shen, R. Zhang, S. Wang, X. Chen, C. Zhao et al., The dynamic evolution of aggregated lithium dendrites in lithium metal batteries. Chin. J. Chem. Eng. 37, 137–143 (2021). https://doi.org/10.1016/j.cjche.2021.05.008
K. Dong, Y. Xu, J. Tan, M. Osenberg, F. Sun et al., Unravelling the mechanism of lithium nucleation and growth and the interaction with the solid electrolyte interface. ACS Energy Lett. 6(5), 1719–1728 (2021). https://doi.org/10.1021/acsenergylett.1c00551
Q. Zhang, Y. Lu, L. Miao, Q. Zhao, K. Xia et al., An alternative to lithium metal anodes: non-dendritic and highly reversible sodium metal anodes for Li-Na hybrid batteries. Angew. Chem. Int. Ed. 57(45), 14796–14800 (2018). https://doi.org/10.1002/anie.201808592
W. Dachraoui, R.-S. Kühnel, C. Battaglia, R. Erni, Nucleation, growth and dissolution of Li metal dendrites and the formation of dead Li in Li-ion batteries investigated by operando electrochemical liquid cell scanning transmission electron microscopy. Nano Energy. 130, 110086 (2024). https://doi.org/10.1016/j.nanoen.2024.110086
E.R. Cooper, M. Li, I. Gentle, Q. Xia, R. Knibbe, A deeper understanding of metal nucleation and growth in rechargeable metal batteries through theory and experiment. Angew. Chem. Int. Ed. 62(51), e202309247 (2023). https://doi.org/10.1002/anie.202309247
G. Feng, Y. Shi, H. Jia, S. Risal, X. Yang et al., Progressive and instantaneous nature of lithium nucleation discovered by dynamic and operando imaging. Sci. Adv. 9(21), eadg6813 (2023). https://doi.org/10.1126/sciadv.adg6813
C. Wang, H. Wang, L. Tao, X. Wang, P. Cao et al., Direct observation of nucleation and growth behaviors of lithium by in situ electron microscopy. ACS Energy Lett. 8(4), 1929–1935 (2023). https://doi.org/10.1021/acsenergylett.3c00180
Z. Hui, S. Yu, S. Wang, G. Hyun, J. Holoubek et al., Nucleation processes at interfaces with both substrate and electrolyte control lithium growth. Nat. Chem. 18(1), 33–42 (2026). https://doi.org/10.1038/s41557-025-01911-y
K. Yan, Z. Lu, H.-W. Lee, F. Xiong, P.-C. Hsu et al., Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth. Nat. Energy. 1, 16010 (2016). https://doi.org/10.1038/nenergy.2016.10
A. Pei, G. Zheng, F. Shi, Y. Li, Y. Cui, Nanoscale nucleation and growth of electrodeposited lithium metal. Nano Lett. 17(2), 1132–1139 (2017). https://doi.org/10.1021/acs.nanolett.6b04755
K. Ishikawa, Y. Ito, S. Harada, M. Tagawa, T. Ujihara, Crystal orientation dependence of precipitate structure of electrodeposited Li metal on Cu current collectors. Cryst. Growth Des. 17(5), 2379–2385 (2017). https://doi.org/10.1021/acs.cgd.6b01710
P. Bai, J. Li, F.R. Brushett, M.Z. Bazant, Transition of lithium growth mechanisms in liquid electrolytes. Energy Environ. Sci. 9(10), 3221–3229 (2016). https://doi.org/10.1039/c6ee01674j
P. Bai, J. Guo, M. Wang, A. Kushima, L. Su et al., Interactions between lithium growths and nanoporous ceramic separators. Joule. 2(11), 2434–2449 (2018). https://doi.org/10.1016/j.joule.2018.08.018
A. Kushima, K.P. So, C. Su, P. Bai, N. Kuriyama et al., Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: root growth, dead lithium and lithium flotsams. Nano Energy. 32, 271–279 (2017). https://doi.org/10.1016/j.nanoen.2016.12.001
M. Sadd, S. Xiong, J.R. Bowen, F. Marone, A. Matic, Investigating microstructure evolution of lithium metal during plating and stripping via operando X-ray tomographic microscopy. Nat. Commun. 14(1), 854 (2023). https://doi.org/10.1038/s41467-023-36568-z
X.-R. Chen, Y.-X. Yao, C. Yan, R. Zhang, X.-B. Cheng et al., A diffusion: reaction competition mechanism to tailor lithium deposition for lithium-metal batteries. Angew. Chem. Int. Ed. 59(20), 7743–7747 (2020). https://doi.org/10.1002/anie.202000375
S. Jo, B. Kwon, J. Oh, J. Lee, K. Park et al., The roles of nucleation and growth kinetics in determining Li metal morphology for Li metal batteries: columnar versus spherical growth. J. Mater. Chem. A 10(10), 5520–5529 (2022). https://doi.org/10.1039/D1TA09481E
H. Wang, E. Matios, J. Luo, W. Li, Combining theories and experiments to understand the sodium nucleation behavior towards safe sodium metal batteries. Chem. Soc. Rev. 49(12), 3783–3805 (2020). https://doi.org/10.1039/D0CS00033G
P.M. Bayley, N.M. Trease, C.P. Grey, Insights into electrochemical sodium metal deposition as probed with in situ 23Na NMR. J. Am. Chem. Soc. 138(6), 1955–1961 (2016). https://doi.org/10.1021/jacs.5b12423
G. Zou, J. Wang, Y. Sun, W. Yang, T. Niu et al., A nanotwinned-alloy strategy enables fast sodium deposition dynamics. Nat. Commun. 16, 1795 (2025). https://doi.org/10.1038/s41467-025-56957-w
R. Rodriguez, K.E. Loeffler, S.S. Nathan, J.K. Sheavly, A. Dolocan et al., In situ optical imaging of sodium electrodeposition: effects of fluoroethylene carbonate. ACS Energy Lett. 2(9), 2051–2057 (2017). https://doi.org/10.1021/acsenergylett.7b00500
Y. Yui, M. Hayashi, J. Nakamura, In situ microscopic observation of sodium deposition/dissolution on sodium electrode. Sci. Rep. 6, 22406 (2016). https://doi.org/10.1038/srep22406
J. Song, G. Jeong, A.-J. Lee, J.H. Park, H. Kim et al., Dendrite-free polygonal sodium deposition with excellent interfacial stability in a NaAlCl4–2SO2 inorganic electrolyte. ACS Appl. Mater. Interfaces. 7(49), 27206–27214 (2015). https://doi.org/10.1021/acsami.5b08111
J. Hu, H. Wang, S. Wang, Y. Lei, L. Qin et al., Electrochemical deposition mechanism of sodium and potassium. Energy Storage Mater. 36, 91–98 (2021). https://doi.org/10.1016/j.ensm.2020.12.017
L. Porz, T. Swamy, B.W. Sheldon, D. Rettenwander, T. Frömling et al., Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7(20), 1701003 (2017). https://doi.org/10.1002/aenm.201701003
D. Cao, X. Sun, Q. Li, A. Natan, P. Xiang et al., Lithium dendrite in all-solid-state batteries: growth mechanisms, suppression strategies, and characterizations. Matter. 3(1), 57–94 (2020). https://doi.org/10.1016/j.matt.2020.03.015
H. Liu, X.-B. Cheng, J.-Q. Huang, H. Yuan, Y. Lu et al., Controlling dendrite growth in solid-state electrolytes. ACS Energy Lett. 5(3), 833–843 (2020). https://doi.org/10.1021/acsenergylett.9b02660
Z. Gu, D. Song, S. Luo, H. Liu, X. Sun et al., Insights into the anode-initiated and grain boundary-initiated mechanisms for dendrite formation in all-solid-state lithium metal batteries. Adv. Energy Mater. 13(45), 2302945 (2023). https://doi.org/10.1002/aenm.202302945
F. Mo, J. Ruan, S. Sun, Z. Lian, S. Yang et al., Inside or outside: origin of lithium dendrite formation of all solid-state electrolytes. Adv. Energy Mater. 9(40), 1902123 (2019). https://doi.org/10.1002/aenm.201902123
H. Liu, Y. Chen, P.-H. Chien, G. Amouzandeh, D. Hou et al., Dendrite formation in solid-state batteries arising from lithium plating and electrolyte reduction. Nat. Mater. 24(4), 581–588 (2025). https://doi.org/10.1038/s41563-024-02094-6
H. Wang, H. Gao, X. Chen, J. Zhu, W. Li et al., Linking the defects to the formation and growth of Li dendrite in all-solid-state batteries. Adv. Energy Mater. 11(42), 2102148 (2021). https://doi.org/10.1002/aenm.202102148
E. Kazyak, R. Garcia-Mendez, W.S. LePage, A. Sharafi, A.L. Davis et al., Li penetration in ceramic solid electrolytes: operando microscopy analysis of morphology, propagation, and reversibility. Matter. 2(4), 1025–1048 (2020). https://doi.org/10.1016/j.matt.2020.02.008
C. Yildirim, F. Flatscher, S. Ganschow, A. Lassnig, C. Gammer et al., Understanding the origin of lithium dendrite branching in Li6.5La3Zr1.5Ta0.5O12 solid-state electrolyte via microscopy measurements. Nat. Commun. 15(1), 8207 (2024). https://doi.org/10.1038/s41467-024-52412-4
L. Zhang, T. Yang, C. Du, Q. Liu, Y. Tang et al., Lithium whisker growth and stress generation in an in situ atomic force microscope-environmental transmission electron microscope set-up. Nat. Nanotechnol. 15(2), 94–98 (2020). https://doi.org/10.1038/s41565-019-0604-x
H. Gao, X. Ai, H. Wang, W. Li, P. Wei et al., Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption. Nat. Commun. 13(1), 5050 (2022). https://doi.org/10.1038/s41467-022-32732-z
F. Sun, L. Duchêne, M. Osenberg, S. Risse, C. Yang et al., Na electrodeposits: a new decaying mechanism for all-solid-state Na batteries revealed by synchrotron X-ray tomography. Nano Energy. 82, 105762 (2021). https://doi.org/10.1016/j.nanoen.2021.105762
L. Geng, D. Xue, J. Yao, Q. Dai, H. Sun et al., Morphodynamics of dendrite growth in alumina based all solid-state sodium metal batteries. Energy Environ. Sci. 16(6), 2658–2668 (2023). https://doi.org/10.1039/D3EE00237C
Z. Gao, Y. Bai, J. Feng, J. Yang, P. Liu et al., Controlling sodium dendrite growth via grain boundaries in Na3Zr2Si2PO12 electrolyte. Adv. Energy Mater. 14(20), 2304488 (2024). https://doi.org/10.1002/aenm.202304488
S. Yang, N. Li, E. Zhao, C. Wang, J. He et al., Imaging dendrite growth in solid-state sodium batteries using fluorescence tomography technology. Sci. Adv. 10(47), eadr0676 (2024). https://doi.org/10.1126/sciadv.adr0676
Z. Ding, Y. Tang, T. Ortmann, J.K. Eckhardt, Y. Dai et al., The impact of microstructure on filament growth at the sodium metal anode in all-solid-state sodium batteries. Adv. Energy Mater. 13(48), 2302322 (2023). https://doi.org/10.1002/aenm.202302322
T. Ortmann, T. Fuchs, J.K. Eckhardt, Z. Ding, Q. Ma et al., Deposition of sodium metal at the copper-NaSICON interface for reservoir-free solid-state sodium batteries. Adv. Energy Mater. 14(15), 2302729 (2024). https://doi.org/10.1002/aenm.202302729
Q. Liu, L. Zhang, H. Sun, L. Geng, Y. Li et al., In situ observation of sodium dendrite growth and concurrent mechanical property measurements using an environmental transmission electron microscopy–atomic force microscopy (ETEM-AFM) platform. ACS Energy Lett. 5(8), 2546–2559 (2020). https://doi.org/10.1021/acsenergylett.0c01214
A. Wang, Q. Zhang, W. Li, K. Zhang, C. Dong et al., Electrochemical–mechanical evolution of dendrites and cracks in Na3Zr2Si2PO12 ceramic solid electrolytes. Adv. Energy Mater. 15(36), e02156 (2025). https://doi.org/10.1002/aenm.202502156
Q. Ma, T. Ortmann, A. Yang, D. Sebold, S. Burkhardt et al., Enhancing the dendrite tolerance of NaSICON electrolytes by suppressing edge growth of Na electrode along ceramic surface. Adv. Energy Mater. 12(40), 2201680 (2022). https://doi.org/10.1002/aenm.202201680
H. Liu, X.-B. Cheng, Z. Jin, R. Zhang, G. Wang et al., Recent advances in understanding dendrite growth on alkali metal anodes. EnergyChem. 1(1), 100003 (2019). https://doi.org/10.1016/j.enchem.2019.100003
M. Wang, X. Guo, R. Luo, X. Jiang, Y. Tang et al., The nucleation and growth mechanism of spherical Li for advanced Li metal anodes—a review. Chem. Commun. 61(19), 3777–3793 (2025). https://doi.org/10.1039/D4CC06729K
Y. Liu, X. Xu, M. Sadd, O.O. Kapitanova, V.A. Krivchenko et al., Insight into the critical role of exchange current density on electrodeposition behavior of lithium metal. Adv. Sci. 8(5), 2003301 (2021). https://doi.org/10.1002/advs.202003301
A.J. Bard, L.R. Faulkner, Electrochemical Methods: Fundamentals and Applications, 2nd edn. (Wiley, New York, 2001), pp.305–316
Y. Lu, C.-Z. Zhao, H. Yuan, X.-B. Cheng, J.-Q. Huang et al., Critical current density in solid-state lithium metal batteries: mechanism, influences, and strategies. Adv. Funct. Mater. 31(18), 2009925 (2021). https://doi.org/10.1002/adfm.202009925
P. Yang, Dendrite growth on metal anodes: a unified framework bridging diffusion and interfacial kinetics. ACS Energy Lett. 10(10), 5040–5046 (2025). https://doi.org/10.1021/acsenergylett.5c02663
S. Luo, Y. Zhang, X. Liu, Z. Wang, A. Fan et al., Thermal behavior of Li electrode in all-solid-state batteries and improved performance by temperature modulation. Int. J. Heat Mass Transf. 199, 123450 (2022). https://doi.org/10.1016/j.ijheatmasstransfer.2022.123450
B.S. Vishnugopi, F. Hao, A. Verma, P.P. Mukherjee, Double-edged effect of temperature on lithium dendrites. ACS Appl. Mater. Interfaces. 12(21), 23931–23938 (2020). https://doi.org/10.1021/acsami.0c04355
M. Tao, X. Chen, H. Lin, Y. Jin, P. Shan et al., Clarifying the temperature-dependent lithium deposition/stripping process and the evolution of inactive Li in lithium metal batteries. ACS Nano. 17(23), 24104–24114 (2023). https://doi.org/10.1021/acsnano.3c09120
K. Yan, J. Wang, S. Zhao, D. Zhou, B. Sun et al., Temperature-dependent nucleation and growth of dendrite-free lithium metal anodes. Angew. Chem. Int. Ed. 58(33), 11364–11368 (2019). https://doi.org/10.1002/anie.201905251
A. Sharafi, H.M. Meyer, J. Nanda, J. Wolfenstine, J. Sakamoto, Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density. J. Power. Sources. 302, 135–139 (2016). https://doi.org/10.1016/j.jpowsour.2015.10.053
C.D. Fincher, C.E. Athanasiou, C. Gilgenbach, M. Wang, B.W. Sheldon et al., Controlling dendrite propagation in solid-state batteries with engineered stress. Joule. 6(12), 2794–2809 (2022). https://doi.org/10.1016/j.joule.2022.10.011
S. Kalnaus, N.J. Dudney, A.S. Westover, E. Herbert, S. Hackney, Solid-state batteries: the critical role of mechanics. Science. 381(6664), eabg5998 (2023). https://doi.org/10.1126/science.abg5998
H. Xu, S. Yang, B. Li, Pressure effects and countermeasures in solid-state batteries: a comprehensive review. Adv. Energy Mater. 14(16), 2303539 (2024). https://doi.org/10.1002/aenm.202303539
J. Hu, Z. Sun, Y. Gao, P. Li, Y. Wu et al., 3D stress mapping reveals the origin of lithium-deposition heterogeneity in solid-state lithium-metal batteries. Cell Rep. Phys. Sci. 3(7), 100938 (2022). https://doi.org/10.1016/j.xcrp.2022.100938
Q. Li, H. Liu, Y. Ye, K.J. Li, F. Wu et al., The critical importance of stack pressure in batteries. Nat. Energy. 10(9), 1064–1073 (2025). https://doi.org/10.1038/s41560-025-01820-x
P. Barai, K. Higa, V. Srinivasan, Effect of initial state of lithium on the propensity for dendrite formation: a theoretical study. J. Electrochem. Soc. 164(2), A180–A189 (2017). https://doi.org/10.1149/2.0661702jes
P. Barai, K. Higa, V. Srinivasan, Lithium dendrite growth mechanisms in polymer electrolytes and prevention strategies. Phys. Chem. Chem. Phys. 19(31), 20493–20505 (2017). https://doi.org/10.1039/c7cp03304d
X. Wang, W. Zeng, L. Hong, W. Xu, H. Yang et al., Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates. Nat. Energy. 3(3), 227–235 (2018). https://doi.org/10.1038/s41560-018-0104-5
J. Becherer, D. Kramer, R. Mönig, The growth mechanism of lithium dendrites and its coupling to mechanical stress. J. Mater. Chem. A 10(10), 5530–5539 (2022). https://doi.org/10.1039/D1TA10920K
B. Zhang, B. Yuan, X. Yan, X. Han, J. Zhang et al., Atomic mechanism of lithium dendrite penetration in solid electrolytes. Nat. Commun. 16, 1906 (2025). https://doi.org/10.1038/s41467-025-57259-x
X. Shen, R. Zhang, P. Shi, X. Chen, Q. Zhang, How does external pressure shape Li dendrites in Li metal batteries? Adv. Energy Mater. 11(10), 2003416 (2021). https://doi.org/10.1002/aenm.202003416
A. Gupta, E. Kazyak, N. Craig, J. Christensen, N.P. Dasgupta et al., Evaluating the effects of temperature and pressure on Li/PEO-LiTFSI interfacial stability and kinetics. J. Electrochem. Soc. 165(11), A2801–A2806 (2018). https://doi.org/10.1149/2.0901811jes
P. Barai, K. Higa, V. Srinivasan, Impact of external pressure and electrolyte transport properties on lithium dendrite growth. J. Electrochem. Soc. 165(11), A2654–A2666 (2018). https://doi.org/10.1149/2.0651811jes
J. Cui, X. Chen, Z. Zhou, M. Zuo, Y. Xiao et al., Effect of continuous pressures on electrochemical performance of Si anodes. Mater. Today Energy. 20, 100632 (2021). https://doi.org/10.1016/j.mtener.2020.100632
J.-M. Doux, H. Nguyen, D.H.S. Tan, A. Banerjee, X. Wang et al., Stack pressure considerations for room-temperature all-solid-state lithium metal batteries. Adv. Energy Mater. 10, 1903253 (2020). https://doi.org/10.1002/aenm.201903253
X. Cao, Y. Lu, X. Song, Z. Yuan, F. Wang, Perspective of unstable solid electrolyte interphase induced lithium dendrite growth: role of thermal effect. Electrochim. Acta. 439, 141722 (2023). https://doi.org/10.1016/j.electacta.2022.141722
Z. Hong, V. Viswanathan, Prospect of thermal shock induced healing of lithium dendrite. ACS Energy Lett. 4(5), 1012–1019 (2019). https://doi.org/10.1021/acsenergylett.9b00433
Y. Li, W. Zhao, G. Zhang, S. Shi, Unified picture on temperature dependence of lithium dendrite growth via phase-field simulation. Energy Mater. Adv. 4, 53 (2023). https://doi.org/10.34133/energymatadv.0053
A. Jana, S.I. Woo, K.S.N. Vikrant, R.E. García, Electrochemomechanics of lithium dendrite growth. Energy Environ. Sci. 12(12), 3595–3607 (2019). https://doi.org/10.1039/c9ee01864f
J.A. Dawson, P. Canepa, T. Famprikis, C. Masquelier, M.S. Islam, Atomic-scale influence of grain boundaries on Li-ion conduction in solid electrolytes for all-solid-state batteries. J. Am. Chem. Soc. 140(1), 362–368 (2018). https://doi.org/10.1021/jacs.7b10593
D. Bistri, C.V. Di Leo, A continuum electro-chemo-mechanical gradient theory coupled with damage: application to Li-metal filament growth in all-solid-state batteries. J. Mech. Phys. Solids. 174, 105252 (2023). https://doi.org/10.1016/j.jmps.2023.105252
F. Hao, W. Wang, P.P. Mukherjee, Mechano-electrochemical interaction in solid-state lithium batteries. J. Electrochem. Soc. 167(8), 080513 (2020). https://doi.org/10.1149/1945-7111/ab8a98
R. Raj, J. Wolfenstine, Current limit diagrams for dendrite formation in solid-state electrolytes for Li-ion batteries. J. Power. Sources. 343, 119–126 (2017). https://doi.org/10.1016/j.jpowsour.2017.01.037
G. Li, C.W. Monroe, Dendrite nucleation in lithium-conductive ceramics. Phys. Chem. Chem. Phys. 21(36), 20354–20359 (2019). https://doi.org/10.1039/c9cp03884a
P. Barai, K. Higa, A.T. Ngo, L.A. Curtiss, V. Srinivasan, Mechanical stress induced current focusing and fracture in grain boundaries. J. Electrochem. Soc. 166(10), A1752–A1762 (2019). https://doi.org/10.1149/2.0321910jes
P. Barai, A.T. Ngo, B. Narayanan, K. Higa, L.A. Curtiss et al., The role of local inhomogeneities on dendrite growth in LLZO-based solid electrolytes. J. Electrochem. Soc. 167(10), 100537 (2020). https://doi.org/10.1149/1945-7111/ab9b08
R. Raj, Stack pressure and critical current density in Li-metal cells: the role of mechanical deformation. Acta Mater. 215, 117076 (2021). https://doi.org/10.1016/j.actamat.2021.117076
A. Singla, K.G. Naik, B.S. Vishnugopi, P.P. Mukherjee, Chemo-mechanics interplay dictates interface instability and asymmetry in plating and stripping of sodium metal electrodes. Adv. Funct. Mater. 35(13), 2418033 (2025). https://doi.org/10.1002/adfm.202418033
W. Zaman, L. Zhao, T. Martin, X. Zhang, Z. Wang et al., Temperature and pressure effects on unrecoverable voids in Li metal solid-state batteries. ACS Appl. Mater. Interfaces. 15(31), 37401–37409 (2023). https://doi.org/10.1021/acsami.3c05886
D.S. Jolly, Z. Ning, G.O. Hartley, B. Liu, D.L.R. Melvin et al., Temperature dependence of lithium anode voiding in argyrodite solid-state batteries. ACS Appl. Mater. Interfaces. 13(19), 22708–22716 (2021). https://doi.org/10.1021/acsami.1c06706
M. Zhang, K. Tantratian, S.-Y. Ham, Z. Wang, M. Chouchane et al., Grain selection growth of soft metal in electrochemical processes. Joule. 9(4), 101847 (2025). https://doi.org/10.1016/j.joule.2025.101847
D. Chatterjee, K.G. Naik, B.S. Vishnugopi, P.P. Mukherjee, Electrodeposition stability landscape for solid–solid interfaces. Adv. Sci. 11(6), 2307455 (2024). https://doi.org/10.1002/advs.202307455
A. Verma, H. Kawakami, H. Wada, A. Hirowatari, N. Ikeda et al., Microstructure and pressure-driven electrodeposition stability in solid-state batteries. Cell Rep. Phys. Sci. 2(1), 100301 (2021). https://doi.org/10.1016/j.xcrp.2020.100301
J. Pei, X. Bai, P. Xue, L. Ma, R. Long et al., All-solid-state battery safety in abnormal thermal situations: crack propagation and lithium dendrite growth. Nano Res. Energy. 4(2), e9120155 (2025). https://doi.org/10.26599/nre.2025.9120155
L. He, Q. Sun, L. Lu, S. Adams, Understanding and preventing dendrite growth in lithium metal batteries. ACS Appl. Mater. Interfaces. 13(29), 34320–34331 (2021). https://doi.org/10.1021/acsami.1c08268
G. Zhao, C. Luo, B. Wu, M. Zhang, H. Wang et al., Low-temperature in situ lithiation construction of a lithiophilic p-selective interlayer for solid-state lithium metal batteries. ACS Appl. Mater. Interfaces 15(43), 50508–50521 (2023). https://doi.org/10.1021/acsami.3c11477
L. Suo, Y.-S. Hu, H. Li, M. Armand, L. Chen, A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries. Nat. Commun. 4, 1481 (2013). https://doi.org/10.1038/ncomms2513
Y.-S. Hu, Y. Lu, The mystery of electrolyte concentration: from superhigh to ultralow. ACS Energy Lett. 5(11), 3633–3636 (2020). https://doi.org/10.1021/acsenergylett.0c02234
F. Chen, X. Wang, M. Armand, M. Forsyth, Cationic polymer-in-salt electrolytes for fast metal ion conduction and solid-state battery applications. Nat. Mater. 21(10), 1175–1182 (2022). https://doi.org/10.1038/s41563-022-01319-w
L. Zhang, X. Yin, S. Shen, Y. Liu, T. Li et al., Simultaneously homogenized electric field and ionic flux for reversible ultrahigh-areal-capacity Li deposition. Nano Lett. 20(8), 5662–5669 (2020). https://doi.org/10.1021/acs.nanolett.0c00797
R. Zhang, X. Shen, X.-B. Cheng, Q. Zhang, The dendrite growth in 3D structured lithium metal anodes: electron or ion transfer limitation? Energy Storage Mater. 23, 556–565 (2019). https://doi.org/10.1016/j.ensm.2019.03.029
J. Pu, J. Li, K. Zhang, T. Zhang, C. Li et al., Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits. Nat. Commun. 10(1), 1896 (2019). https://doi.org/10.1038/s41467-019-09932-1
Z. Liang, M.S. Nafis, S. Cho, F. Guo, H. Zhou et al., Pressure-tolerant 3D anodes enable short-circuit prevention and low heat generation in argyrodite solid-state batteries. ACS Energy Lett. 10(5), 2461–2467 (2025). https://doi.org/10.1021/acsenergylett.5c00985
B. Yi, Z. Wei, W. Jia, G. Sun, W. Si et al., Nonstoichiometry induced amorphous grain boundary of Na5SmSi4O12 solid-state electrolyte for long-life dendrite-free sodium metal battery. Nano Lett. 24(29), 8911–8919 (2024). https://doi.org/10.1021/acs.nanolett.4c01743
S. Zhao, H. Wang, Y. Wang, Y. Li, L. Zheng et al., Inhibiting microdomain crystallinity of polymer-based electrolytes toward high-performance solid-state sodium batteries. Nano Energy. 145, 111473 (2025). https://doi.org/10.1016/j.nanoen.2025.111473
A. Parejiya, R. Amin, M.B. Dixit, R. Essehli, C.J. Jafta et al., Improving contact impedance via electrochemical pulses applied to lithium–solid electrolyte interface in solid-state batteries. ACS Energy Lett. 6(10), 3669–3675 (2021). https://doi.org/10.1021/acsenergylett.1c01573
Q. Li, S. Tan, L. Li, Y. Lu, Y. He, Understanding the molecular mechanism of pulse current charging for stable lithium-metal batteries. Sci. Adv. 3(7), e1701246 (2017). https://doi.org/10.1126/sciadv.1701246
D. Qiao, X. Liu, R. Dou, Z. Wen, W. Zhou et al., Quantitative analysis of the inhibition effect of rising temperature and pulse charging on lithium dendrite growth. J. Energy Storage. 49, 104137 (2022). https://doi.org/10.1016/j.est.2022.104137
A. Aryanfar, D. Brooks, B.V. Merinov, W.A. Goddard III., A.J. Colussi et al., Dynamics of lithium dendrite growth and inhibition: pulse charging experiments and Monte Carlo calculations. J. Phys. Chem. Lett. 5(10), 1721–1726 (2014). https://doi.org/10.1021/jz500207a
V. Reisecker, F. Flatscher, L. Porz, C. Fincher, J. Todt et al., Effect of pulse-current-based protocols on the lithium dendrite formation and evolution in all-solid-state batteries. Nat. Commun. 14, 2432 (2023). https://doi.org/10.1038/s41467-023-37476-y
Y. Chen, X. Dou, K. Wang, Y. Han, Lithium dendrites inhibition via diffusion enhancement. Adv. Energy Mater. 9(17), 1900019 (2019). https://doi.org/10.1002/aenm.201900019
K. Shen, Z. Wang, X. Bi, Y. Ying, D. Zhang et al., Magnetic field–suppressed lithium dendrite growth for stable lithium-metal batteries. Adv. Energy Mater. 9(20), 1900260 (2019). https://doi.org/10.1002/aenm.201900260
Y. Chen, X. Dou, K. Wang, Y. Han, Magnetically enhancing diffusion for dendrite-free and long-term stable lithium metal anodes. Green Energy Environ. 7(5), 965–974 (2022). https://doi.org/10.1016/j.gee.2020.12.014
R.S. Longchamps, S. Ge, Z.J. Trdinich, J. Liao, C.-Y. Wang, Battery electronification: intracell actuation and thermal management. Nat. Commun. 15(1), 5373 (2024). https://doi.org/10.1038/s41467-024-49389-5
S. Chen, X. Hu, L. Nie, Y. Yu, W. Liu, Recycling of garnet solid electrolytes with lithium-dendrite penetration by thermal healing. Sci. China Mater. 66(6), 2192–2198 (2023). https://doi.org/10.1007/s40843-022-2371-9
Z. Yu, C. Gan, S. Song, P. Guduru, K.-S. Kim et al., Dendrite suppression in garnet electrolytes via thermally induced compressive stress. Joule. 10(1), 102232 (2026). https://doi.org/10.1016/j.joule.2025.102232
Z. Gao, J. Yang, G. Li, T. Ferber, J. Feng et al., TiO2 as second phase in Na3Zr2Si2PO12 to suppress dendrite growth in sodium metal solid-state batteries. Adv. Energy Mater. 12(9), 2103607 (2022). https://doi.org/10.1002/aenm.202103607
M. Feng, C.-T. Yang, Y. Qi, The critical stack pressure to alter void generation at Li/solid-electrolyte interfaces during stripping. J. Electrochem. Soc. 169(9), 090526 (2022). https://doi.org/10.1149/1945-7111/ac91aa
L. Ye, X. Li, A dynamic stability design strategy for lithium metal solid state batteries. Nature. 593(7858), 218–222 (2021). https://doi.org/10.1038/s41586-021-03486-3
K. Yan, S. Zhao, J. Zhang, J. Safaei, X. Yu et al., Dendrite-free sodium metal batteries enabled by the release of contact strain on flexible and sodiophilic matrix. Nano Lett. 20(8), 6112–6119 (2020). https://doi.org/10.1021/acs.nanolett.0c02215