Tunable Optical Metamaterial Enables Steganography, Rewriting, and Multilevel Information Storage
Corresponding Author: Wen Jung Li
Nano-Micro Letters,
Vol. 18 (2026), Article Number: 58
Abstract
In the realm of secure information storage, optical encryption has emerged as a vital technique, particularly with the miniaturization of encryption devices. However, many existing systems lack the necessary reconfigurability and dynamic functionality. This study presents a novel approach through the development of dynamic optical-to-chemical energy conversion metamaterials, which enable enhanced steganography and multilevel information storage. We introduce a micro-dynamic multiple encryption device that leverages programmable optical properties in coumarin-based metamaterials, achieved through a direct laser writing grayscale gradient strategy. This methodology allows for the dynamic regulation of photoluminescent characteristics and cross-linking networks, facilitating innovative steganographic techniques under varying light conditions. The integration of a multi-optical field control system enables real-time adjustments to the material’s properties, enhancing the device’s reconfigurability and storage capabilities. Our findings underscore the potential of these metamaterials in advancing the field of microscale optical encryption, paving the way for future applications in dynamic storage and information security.
Highlights:
1 Proposed a dynamic grayscale gradient modulation system enabling multi-information analysis and encryption under multi-optical fields, establishing a new paradigm for multi-dimensional encryption of collaborative multispectral information.
2 Developed coumarin-based photo-responsive in situ reconstruction technology and constructed a multi-optical field coupled control system to achieve dynamic configuration of multi-information carriers.
3 Designed and fabricated a micro-dynamic multiple encryption device with integrated functions for information writing, erasing and rewriting, realizing stable information storage and dynamic destruction through micro/nano-optical keys.
Keywords
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References
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P. Li, Q. Li, W. Tang, W. Wang, W. Zhang et al., Scalable parallel ultrafast optical random bit generation based on a single chaotic microcomb. Light Sci. Appl. 13(1), 66 (2024). https://doi.org/10.1038/s41377-024-01411-7
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A. Arbabi, A. Faraon, Advances in optical metalenses. Nat. Photonics 17(1), 16–25 (2023). https://doi.org/10.1038/s41566-022-01108-6
C.L. Panuski, I. Christen, M. Minkov, C.J. Brabec, S. Trajtenberg-Mills et al., A full degree-of-freedom spatiotemporal light modulator. Nat. Photonics 16(12), 834–842 (2022). https://doi.org/10.1038/s41566-022-01086-9
M. Song, D. Wang, Z.A. Kudyshev, Y. Xuan, Z. Wang et al., Enabling optical steganography, data storage, and encryption with plasmonic colors. Laser Photonics Rev. 15(3), 2000343 (2021). https://doi.org/10.1002/lpor.202000343
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W. Zhang, H. Wang, A.T.L. Tan, A.S. Ranganath, B. Zhang et al., Stiff shape memory polymers for high-resolution reconfigurable nanophotonics. Nano Lett. 22(22), 8917–8924 (2022). https://doi.org/10.1021/acs.nanolett.2c03007
Q. Zhang, L. Yang, Y. Gao, Y. Xiang, H. Li et al., Multi-color solid-state photoluminescence from orthogonally multi-stimuli-responsive organic molecule for advanced information storage and encryption. Chem. Eng. J. 459, 141666 (2023). https://doi.org/10.1016/j.cej.2023.141666
H. Wang, W. Zhang, D. Ladika, H. Yu, D. Gailevičius et al., Two-photon polymerization lithography for optics and photonics: fundamentals, materials, technologies, and applications. Adv. Funct. Mater. 33(39), 2214211 (2023). https://doi.org/10.1002/adfm.202214211
H. Liu, H. Wang, H. Wang, J. Deng, Q. Ruan et al., High-order photonic cavity modes enabled 3D structural colors. ACS Nano 16(5), 8244–8252 (2022). https://doi.org/10.1021/acsnano.2c01999
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F. Bian, L. Sun, H. Chen, Y. Wang, L. Wang et al., Bioinspired perovskite nanocrystals-integrated photonic crystal microsphere arrays for information security. Adv. Sci. 9(9), e2105278 (2022). https://doi.org/10.1002/advs.202105278
N.A. Rubin, A. Zaidi, A.H. Dorrah, Z. Shi, F. Capasso, Jones matrix holography with metasurfaces. Sci. Adv. 7(33), eabg7488 (2021). https://doi.org/10.1126/sciadv.abg7488
Y. Xi, F. Zhang, Y. Ma, V.M. Prabhu, Y. Liu, Finely tunable dynamical coloration using bicontinuous micrometer-domains. Nat. Commun. 13(1), 3619 (2022). https://doi.org/10.1038/s41467-022-31020-0
X. Luo, B. Tian, Y. Zhai, H. Guo, S. Liu et al., Room-temperature phosphorescent materials derived from natural resources. Nat. Rev. Chem. 7(11), 800–812 (2023). https://doi.org/10.1038/s41570-023-00536-4
Y. Xie, G. Sun, J. Li, L. Sun, Multimode emission from lanthanide-based metal–organic frameworks for advanced information encryption. Adv. Funct. Mater. 33(43), 2303663 (2023). https://doi.org/10.1002/adfm.202303663
Y. Tian, H. Peng, Q. Wei, Y. Chen, J. Xia et al., Moisture-induced reversible structure conversion of zero-dimensional organic cuprous bromide hybrids for multiple photoluminescent anti-counterfeiting, information encryption and rewritable luminescent paper. Chem. Eng. J. 458, 141436 (2023). https://doi.org/10.1016/j.cej.2023.141436
M. Song, L. Feng, P. Huo, M. Liu, C. Huang et al., Versatile full-colour nanopainting enabled by a pixelated plasmonic metasurface. Nat. Nanotechnol. 18(1), 71–78 (2023). https://doi.org/10.1038/s41565-022-01256-4
H. Yang, K. Ou, H. Wan, Y. Hu, Z. Wei et al., Metasurface-empowered optical cryptography. Mater. Today 67, 424–445 (2023). https://doi.org/10.1016/j.mattod.2023.06.003
X. Liu, J. Liu, B. Wei, D. Yang, L. Luo et al., Bio-inspired highly brilliant structural colors and derived photonic superstructures for information encryption and fluorescence enhancement. Adv. Sci. 10(24), 2302240 (2023). https://doi.org/10.1002/advs.202302240
T. Mori, H. Wang, W. Zhang, C.C. Ser, D. Arora et al., Pick and place process for uniform shrinking of 3D printed micro- and nano-architected materials. Nat. Commun. 14(1), 1–9 (2023). https://doi.org/10.1038/s41467-023-41535-9
M. Lu, X. Zhang, D. Xu, N. Li, Y. Zhao, Encoded structural color microneedle patches for multiple screening of wound small molecules. Adv. Mater. 35(19), 2211330 (2023). https://doi.org/10.1002/adma.202211330
M. Liu, J. Fu, S. Yang, Y. Wang, L. Jin et al., Janus microdroplets with tunable self-recoverable and switchable reflective structural colors. Adv. Mater. 35(5), e2207985 (2023). https://doi.org/10.1002/adma.202207985
L. Zhang, S. Lin, Q. Zhou, J. Xue, B. Xu et al., Speckle-based optical encryption with complex-amplitude coding and deep learning. Opt. Express 31(21), 35293–35304 (2023). https://doi.org/10.1364/OE.503694
X. Zhan, Z. Zhou, W. Zhou, Y. Yan, J. Yao et al., Wavelength-tunable circularly polarized laser arrays for multidimensional information encryption. Adv. Opt. Mater. 11(13), 2200872 (2023). https://doi.org/10.1002/adom.202200872
S. Liu, X. Wang, J. Ni, Y. Cao, J. Li et al., Optical encryption in the photonic orbital angular momentum dimension via direct-laser-writing 3D chiral metahelices. Nano Lett. 23(6), 2304–2311 (2023). https://doi.org/10.1021/acs.nanolett.2c04860
C. Wang, D. Zhang, J. Yue, X. Zhang, H. Lin et al., Dual-layer optical encryption fluorescent polymer waveguide chip based on optical pulse-code modulation technique. Nat. Commun. 14, 4578 (2023). https://doi.org/10.1038/s41467-023-40341-7
X. Zhou, H. Wang, S. Liu, H. Wang, J.Y.E. Chan et al., Arbitrary engineering of spatial caustics with 3D-printed metasurfaces. Nat. Commun. 15(1), 3719 (2024). https://doi.org/10.1038/s41467-024-48026-5
J. Shin, H. Kim, S. Sundaram, J. Jeong, B.-I. Park et al., Vertical full-colour micro-LEDs via 2D materials-based layer transfer. Nature 614(7946), 81–87 (2023). https://doi.org/10.1038/s41586-022-05612-1
T. Alexoudi, G.T. Kanellos, N. Pleros, Optical RAM and integrated optical memories: a survey. Light Sci. Appl. 9, 91 (2020). https://doi.org/10.1038/s41377-020-0325-9
Y. Wu, X. Chen, W. Wu, Multiple stimuli-response polychromatic carbon dots for advanced information encryption and safety. Small 19(10), 2206709 (2023). https://doi.org/10.1002/smll.202206709
K. Du, J. Zhu, Y. Du, X. Xu, H. Gao et al., Hybrid encoding strategy of nanostructures for high-performance security information encryption. Adv. Opt. Mater. 11(9), 2300046 (2023). https://doi.org/10.1002/adom.202300046
M. Wang, C. Nie, J. Liu, S. Wu, Organic–inorganic semi-interpenetrating networks with orthogonal light- and magnetic-responsiveness for smart photonic gels. Nat. Commun. 14(1), 1–10 (2023). https://doi.org/10.1038/s41467-023-36706-7
T.-H. Xiong, W. Li, Q.-Y. Yi, P.-H. Su, Y.-X. Peng et al., A temperature-tunable chirality-selective meta-absorber for electromagnetic encrypted imaging. Appl. Phys. Lett. 123(9), 091701 (2023). https://doi.org/10.1063/5.0163751
M. Zhang, Y. Lee, Z. Zheng, M.T.A. Khan, X. Lyu et al., Micro- and nanofabrication of dynamic hydrogels with multichannel information. Nat. Commun. 14(1), 8208 (2023). https://doi.org/10.1038/s41467-023-43921-9
H. Yang, S. Li, J. Zheng, G. Chen, W. Wang et al., Erasable, rewritable, and reprogrammable dual information encryption based on photoluminescent supramolecular host-guest recognition and hydrogel shape memory. Adv. Mater. 35(40), e2301300 (2023). https://doi.org/10.1002/adma.202301300
A. Gao, F. Sun, Y. Duan, Y. Zhang, X. Liu et al., Programmable encryption based on photochromism of spiropyrans and donor–acceptor stenhouse adducts. Adv. Funct. Mater. 34(26), 2316457 (2024). https://doi.org/10.1002/adfm.202316457
S. Lee, J.W. Park, J. Jang, J.W. Oh, G. Kim et al., Rewritable triple-mode light-emitting display. Nano-Micro Lett. 17(1), 183 (2025). https://doi.org/10.1007/s40820-025-01686-4
Q. Wang, B. Lin, M. Chen, C. Zhao, H. Tian et al., A dynamic assembly-induced emissive system for advanced information encryption with time-dependent security. Nat. Commun. 13(1), 4185 (2022). https://doi.org/10.1038/s41467-022-31978-x
M. Zhang, A. Pal, Z. Zheng, G. Gardi, E. Yildiz et al., Hydrogel muscles powering reconfigurable micro-metastructures with wide-spectrum programmability. Nat. Mater. 22(10), 1243–1252 (2023). https://doi.org/10.1038/s41563-023-01649-3
Y. Zhang, H. Yu, X. Zhang, J. Zheng, J. Wang et al., A novel multifunctional material for constructing 3D multi-response structures using programmable two-photon laser fabrication. Adv. Funct. Mater. 34(28), 2313922 (2024). https://doi.org/10.1002/adfm.202313922