Hydrogel Fiber Evaporator with Vertical Channels Integrated with Dual Heat Supply/Insulation Model for Continuous Solar Desalination
Corresponding Author: Xiansheng Zhang
Nano-Micro Letters,
Vol. 18 (2026), Article Number: 261
Abstract
Hydrogel-based evaporators offer unique advantages for seawater desalination, yet the high verticalization of water transport channels remains significantly constrained by the random arrangement of polymers. Herein, a versatile and scalable “wet-spinning hydrogel fibers assisted with constrained alignment (HFCA)” strategy is proposed to fabricate hierarchically porous hydrogel fiber evaporator, achieving the perfectly vertical, large-scale spaces between adjacent fibers and small-scale pores within the hydrogel itself. The synergistic role of multiscale pores significantly enhances the siphon effect between fibers and the water transport capacity, while improving thermal localization, light absorption, and salt flux. Moreover, rather than employing the popular “heat isolation model”, a dual “heat supply/insulation model” is introduced for the first time in a three-dimensional evaporator, where a novel heating layer providing additional heat to the bulk water, along with an insulation layer minimizing heat loss. Together, these components create a positive net energy balance, transforming the single cold into a combined cold/hot evaporation manner on the side surface. Using this model, the HFCA evaporator exhibits the high evaporation rate (8.09 kg m−2 h−1, 1 KW m−2) among the reported hydrogel-based evaporators and achieves exceptional outdoor evaporation (64.74 kg m−2 for 9 h), accompanied with salt tolerance, anti-oil fouling, and self-cleaning capacities.
Highlights:
1 A versatile yet scalable “wet-spinning hydrogel fibers assisted with constrained alignment (HFCA)” strategy is proposed to achieve a highly vertical hydrogel fiber aggregate with multiscale pore structure.
2 The dual “heat supply/insulation model” transforms the conventional single cold evaporation into cold/hot evaporation on the side surface for the first time, maximizing energy utilization of 3D evaporator.
3 HFCA makes a breakthrough in verticalization of water transport channels and maximum utilization of energy, accompanied with superior salt tolerance, anti-oil fouling and self-cleaning ability.
Keywords
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References
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T. Wang, M. Li, H. Xu, X. Wang, M. Jia et al., MXene sediment-based poly(vinyl alcohol)/sodium alginate aerogel evaporator with vertically aligned channels for highly efficient solar steam generation. Nano-Micro Lett. 16(1), 220 (2024). https://doi.org/10.1007/s40820-024-01433-1
C. Ge, D. Xu, Y. Song, Y. Liu, X. Feng et al., Fibrous solar evaporator with tunable water flow for efficient, self-operating, and sustainable hydroelectricity generation. Adv. Funct. Mater. 34(40), 2403608 (2024). https://doi.org/10.1002/adfm.202403608
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G. Yin, J. Wu, C. Qi, X. Zhou, Z.-Z. Yu et al., Pickering emulsion-driven MXene/silk fibroin hydrogels with programmable functional networks for EMI shielding and solar evaporation. Nano-Micro Lett. 17(1), 312 (2025). https://doi.org/10.1007/s40820-025-01818-w
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Y. Yang, Y. He, S. Yang, D. Dong, J. Zhang et al., Tough, durable and saline-tolerant CNT@Gel-nacre nanocomposite for interfacial solar steam generation. J. Colloid Interface Sci. 650, 182–192 (2023). https://doi.org/10.1016/j.jcis.2023.06.148
X. Liu, F. Chen, Y. Li, H. Jiang, D.D. Mishra et al., 3D hydrogel evaporator with vertical radiant vessels breaking the trade-off between thermal localization and salt resistance for solar desalination of high-salinity. Adv. Mater. 34(36), e2203137 (2022). https://doi.org/10.1002/adma.202203137
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L. Ren, Q. Zhang, G. Zhao, T. Chen, Y. Wang et al., Interconnected porous fabric-based scalable evaporator with asymmetric wetting properties for high-yield and salt-rejecting solar brine treatment. Adv. Fiber Mater. 6(4), 1162–1173 (2024). https://doi.org/10.1007/s42765-024-00409-5
A. Hu, Y. Zhao, Q. Hu, C. Chen, X. Lu et al., Highly efficient solar steam evaporation via elastic polymer covalent organic frameworks monolith. Nat. Commun. 15(1), 9484 (2024). https://doi.org/10.1038/s41467-024-53902-1
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Y. Wang, X. Wu, X. Yang, G. Owens, H. Xu, Reversing heat conduction loss: extracting energy from bulk water to enhance solar steam generation. Nano Energy 78, 105269 (2020). https://doi.org/10.1016/j.nanoen.2020.105269
L. Lei, S. Meng, Y. Si, S. Shi, H. Wu et al., Wettability gradient-induced diode: MXene-engineered membrane for passive-evaporative cooling. Nano-Micro Lett. 16(1), 159 (2024). https://doi.org/10.1007/s40820-024-01359-8
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D. Wei, C. Wang, J. Zhang, H. Zhao, Y. Asakura et al., Water activation in solar-powered vapor generation. Adv. Mater. 35(47), 2212100 (2023). https://doi.org/10.1002/adma.202212100
H. Yang, Z. Hu, S. Wu, J. Yan, K. Cen et al., Directional-thermal-conductive phase change composites enabling efficient and durable water-electricity co-generation beyond daytime. Adv. Energy Mater. 14(43), 2470191 (2024). https://doi.org/10.1002/aenm.202470191
W. Li, X. Tian, X. Li, J. Liu, C. Li et al., An environmental energy-enhanced solar steam evaporator derived from MXene-decorated cellulose acetate cigarette filter with ultrahigh solar steam generation efficiency. J. Colloid Interface Sci. 606, 748–757 (2022). https://doi.org/10.1016/j.jcis.2021.08.043
W. Li, X. Tian, X. Li, S. Han, C. Li et al., Ultrahigh solar steam generation rate of a vertically aligned reduced graphene oxide foam realized by dynamic compression. J. Mater. Chem. A 9(26), 14859–14867 (2021). https://doi.org/10.1039/d1ta03014k
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X. Zhang, L. Sun, X. Wang, S. Zou, C. Cao et al., Hydrogel-based 3D evaporator with cross-linked fixation by carbon dots for ultra-high and stable solar steam generation. Chem. Eng. J. 497, 154793 (2024). https://doi.org/10.1016/j.cej.2024.154793
Y. Xiao, B. Liu, D. Li, X. Zheng, J. Li et al., Biomimetic hydrogel evaporator with excellent salt-rejection performance via edge-preferential crystallization and ion-transport effects. Chem. Eng. J. 497, 155038 (2024). https://doi.org/10.1016/j.cej.2024.155038
Y. Liang, J. Guo, J.-J. Li, J. Mao, A.-Q. Xie et al., Robust and flexible 3D photothermal evaporator with heat storage for high-performance solar-driven evaporation. Adv. Sustain. Syst. 6(10), 2200236 (2022). https://doi.org/10.1002/adsu.202200236
L. Chen, Y. Wu, W. Xing, Q. Su, L. Tang et al., Mechanically robust composite hydrogels for high performance solar driven interface evaporation. Chem. Eng. Sci. 267, 118330 (2023). https://doi.org/10.1016/j.ces.2022.118330
X. Fan, Y. Peng, B. Lv, Y. Yang, Z. You et al., A siphon-based spatial evaporation device for efficient salt-free interfacial steam generation. Desalination 552, 116442 (2023). https://doi.org/10.1016/j.desal.2023.116442
Z. Lei, S. Zhu, X. Sun, S. Yu, X. Liu et al., A multiscale porous 3D-fabric evaporator with vertically aligned yarns enables ultra-efficient and continuous water desalination. Adv. Funct. Mater. 32(40), 2205790 (2022). https://doi.org/10.1002/adfm.202205790
X. Han, S. Ding, L. Fan, Y. Zhou, S. Wang, Janus biocomposite aerogels constituted of cellulose nanofibrils and MXenes for application as single-module solar-driven interfacial evaporators. J. Mater. Chem. A 9(34), 18614–18622 (2021). https://doi.org/10.1039/d1ta04991g
M.-H. Sun, C. Li, J. Liu, P. Min, Z.-Z. Yu et al., Three-dimensional mirror-assisted and concave pyramid-shaped solar–thermal steam generator for highly efficient and stable water evaporation and brine desalination. ACS Appl. Mater. Interfaces 15(22), 27120–27129 (2023). https://doi.org/10.1021/acsami.3c02087
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