MXene-Assembled Liquid Metal Hybrid Microparticles for Multifunctional and Stretchable Printed Electronics
Corresponding Author: Shaowu Pan
Nano-Micro Letters,
Vol. 18 (2026), Article Number: 314
Abstract
Stretchable printed electronic devices are essential for the advancement of soft robotics, bioelectronics, and wearable systems. Liquid metals, owing to their high electrical conductivity and intrinsic deformability, have emerged as promising candidates for these applications. However, their limited functionality hinders their integration into multifunctional electronic devices. Here, we present versatile MXene-assembled liquid metal hybrid microparticles (MLHMs), which serve not only as conductive platforms for diverse electronic devices but also as electrochemical electrodes for stretchable energy storage devices. This multifunctionality stems from their unique structure, in which MXene nanosheets self-assemble around liquid metal microparticles via coordination interactions, forming an interconnected hybrid network within the printed pattern. This architecture enables the activation of electrical conductivity in hybrid microparticles at a minimal strain of 2.5%, achieving a high electrical conductivity of 3.7 × 105 S m−1 and excellent stretchability of ~ 700%. The MLHMs demonstrate multifunctionality in stretchable antennas, micro-supercapacitors, electroluminescent devices, and flexible printed circuit boards, enabling wireless power transmission, energy storage, and stretchable and interactive display. These hybrids represent versatile material units for advancing stretchable and integrated electronic systems.
Highlights:
1 MXene-assembled liquid metal hybrid microparticles were developed by integrating MXene nanosheets with liquid metal particles through Ga–O–Ti coordination bonding.
2 These hybrid microparticles can be precisely patterned onto diverse substrates via printing techniques, achieving high conductivity of 3.7 × 105 S m−1.
3 Their multifunctionality is demonstrated in applications including wireless power transmission, energy storage, and interactive display systems.
Keywords
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References
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J.C. Yang, J. Mun, S.Y. Kwon, S. Park, Z. Bao, Electronic skin: recent progress and future prospects for skin-attachable devices for health monitoring, robotics, and prosthetics. Adv. Mater. 31(48), 1904765 (2019). https://doi.org/10.1002/adma.201904765
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K.Y. Chung, B. Xu, D. Tan, Q. Yang, Z. Li et al., Naturally crosslinked biocompatible carbonaceous liquid metal aqueous ink printing wearable electronics for multi-sensing and energy harvesting. Nano-Micro Lett. 16(1), 149 (2024). https://doi.org/10.1007/s40820-024-01362-z
J. Qiu, R. Yu, X. Du, T. Zhou, Y. Chen et al., Liquid metal gel ink with self-activating conductivity for 3D printing of multifunctional electronics. Small 21(29), 2502722 (2025). https://doi.org/10.1002/smll.202502722
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S. Zheng, X. Wang, W. Li, Z. Liu, Q. Li et al., Pressure-stamped stretchable electronics using a nanofibre membrane containing semi-embedded liquid metal ps. Nat. Electron. 7(7), 576–585 (2024). https://doi.org/10.1038/s41928-024-01194-0
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S. Lee, S.A. Jaseem, N. Atar, M. Wang, J.Y. Kim et al., Connecting the dots: sintering of liquid metal ps for soft and stretchable conductors. Chem. Rev. 125(6), 3551–3585 (2025). https://doi.org/10.1021/acs.chemrev.4c00850
G.-H. Lee, Y.R. Lee, H. Kim, D.A. Kwon, H. Kim et al., Rapid meniscus-guided printing of stable semi-solid-state liquid metal microgranular-p for soft electronics. Nat. Commun. 13, 2643 (2022). https://doi.org/10.1038/s41467-022-30427-z
S. Lee, G.-H. Lee, I. Kang, W. Jeon, S. Kim et al., Phase-change metal ink with pH-controlled chemical sintering for versatile and scalable fabrication of variable stiffness electronics. Sci. Adv. 11(22), eadv4921 (2025). https://doi.org/10.1126/sciadv.adv4921
Z. Lin, X. Qiu, Z. Cai, J. Li, Y. Zhao et al., High internal phase emulsions gel ink for direct-ink-writing 3D printing of liquid metal. Nat. Commun. 15(1), 4806 (2024). https://doi.org/10.1038/s41467-024-48906-w
P. Wu, J. Fu, Y. Xu, Y. He, Liquid metal microgels for three-dimensional printing of smart electronic clothes. ACS Appl. Mater. Interfaces 14(11), 13458–13467 (2022). https://doi.org/10.1021/acsami.1c22975
G.-H. Lee, H. Woo, C. Yoon, C. Yang, J.-Y. Bae et al., A personalized electronic tattoo for healthcare realized by on-the-spot assembly of an intrinsically conductive and durable liquid-metal composite. Adv. Mater. 34(32), 2270236 (2022). https://doi.org/10.1002/adma.202270236
Q. Lu, T. Fang, C. Ye, Y. Li, M. Wu et al., Highly conductive liquid metal emulsion gels for three-dimensionally printed stretchable electronics. Adv. Sci. 12(36), e03449 (2025). https://doi.org/10.1002/advs.202503449
L. Wang, Y. Lin, C. Yang, Q. Wang, T. Fang et al., Spray-on electronic tattoos with MXene and liquid metal nanocomposites. Chem. Eng. J. 500, 157504 (2024). https://doi.org/10.1016/j.cej.2024.157504
Z.U.D. Babar, V. Iannotti, G. Rosati, A. Zaheer, R. Velotta et al., MXenes in healthcare: synthesis, fundamentals and applications. Chem. Soc. Rev. 54(7), 3387–3440 (2025). https://doi.org/10.1039/d3cs01024d
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu et al., Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23(37), 4248–4253 (2011). https://doi.org/10.1002/adma.201102306
A. VahidMohammadi, J. Rosen, Y. Gogotsi, The world of two-dimensional carbides and nitrides (MXenes). Science 372(6547), eabf1581 (2021). https://doi.org/10.1126/science.abf1581
P. Huang, W.-Q. Han, Recent advances and perspectives of Lewis acidic etching route: an emerging preparation strategy for MXenes. Nano-Micro Lett. 15(1), 68 (2023). https://doi.org/10.1007/s40820-023-01039-z
X. Che, T. Wang, B. Zhang, Z. Zhai, Y. Chen et al., Two-dimensionally nano-capsulating liquid metal for self-sintering and self-oscillating bimorph composites with persistent energy-harvest property. Adv. Funct. Mater. 34(31), 2307830 (2024). https://doi.org/10.1002/adfm.202307830
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